A review on cathode processes and materials for electro-reduction of carbon dioxide in solid oxide electrolysis cells

Y Jiang, F Chen, C Xia - Journal of Power Sources, 2021 - Elsevier
Excessive emission of CO 2 may jeopardize the environment and livelihood of mankind. To
achieve a sustainable future, solid oxide electrolysis cells (SOECs) are increasingly …

Impacts of the Catalyst Structures on CO2 Activation on Catalyst Surfaces

UJ Etim, C Zhang, Z Zhong - Nanomaterials, 2021 - mdpi.com
Utilizing CO2 as a sustainable carbon source to form valuable products requires activating it
by active sites on catalyst surfaces. These active sites are usually in or below the nanometer …

Atomically dispersed Ni(i) as the active site for electrochemical CO2 reduction

HB Yang, SF Hung, S Liu, K Yuan, S Miao, L Zhang… - Nature energy, 2018 - nature.com
Electrochemical reduction of CO2 to chemical fuel offers a promising strategy for managing
the global carbon balance, but presents challenges for chemistry due to the lack of effective …

On the origin of the elusive first intermediate of CO2 electroreduction

IV Chernyshova, P Somasundaran… - Proceedings of the …, 2018 - National Acad Sciences
We resolve the long-standing controversy about the first step of the CO2 electroreduction to
fuels in aqueous electrolytes by providing direct spectroscopic evidence that the first …

CO2 Reduction on Transition Metal (Fe, Co, Ni, and Cu) Surfaces: In Comparison with Homogeneous Catalysis

C Liu, TR Cundari, AK Wilson - The Journal of Physical Chemistry …, 2012 - ACS Publications
Reduction of CO2 to CO on Fe, Co, Ni, and Cu surfaces has been studied using density
functional theory (DFT) methods. Three reaction steps were studied:(a) adsorption of CO2 …

Density Functional Theory Study for Catalytic Activation and Dissociation of CO2 on Bimetallic Alloy Surfaces

J Ko, BK Kim, JW Han - The Journal of Physical Chemistry C, 2016 - ACS Publications
CO2 has a potentially bright future as a carbon resource because it is very cheap and
abundant. The conversion technology of CO2 into useful chemicals therefore has gained …

Carbon dioxide hydrogenation over nickel-, ruthenium-, and copper-based catalysts: Review of kinetics and mechanism

K Jalama - Catalysis Reviews, 2017 - Taylor & Francis
This study critically reviews the mechanism of CO2 hydrogenation over Ni, Ru, and Cu, and
the effect of catalyst properties and operating conditions on reaction kinetics. Most studies …

Symmetry-breaking sites for activating linear carbon dioxide molecules

H Li, J Zhao, L Luo, J Du, J Zeng - Accounts of Chemical Research, 2021 - ACS Publications
Conspectus CO2 is not only a greenhouse gas but also a pivotal carbon source as a
promising supplement to fossil fuels. Both the environment and energy crises have …

Surface chemistry of CO2–Adsorption of carbon dioxide on clean surfaces at ultrahigh vacuum

U Burghaus - Progress in surface science, 2014 - Elsevier
Carbon dioxide chemistry has attracted significant interest in recent years. Although the field
is diverse, a current and more comprehensive review of the surface science literature may …

Recent Developments in the Modelling of Heterogeneous Catalysts for CO2 Conversion to Chemicals

N Podrojková, V Sans, A Oriňak, R Oriňaková - ChemCatChem, 2020 - Wiley Online Library
Density functional theory (DFT) of the CO2 behavior on the catalyst surface provides
valuable insights about the C= O bond activation, information about adsorption and …