The interpretation of XPS spectra: Insights into materials properties

PS Bagus, ES Ilton, CJ Nelin - Surface Science Reports, 2013 - Elsevier
We review basic and advanced concepts needed for the correct analysis of XPS features.
We place these concepts on rigorous foundations and explore their physical and chemical …

Use and mis-use of x-ray photoemission spectroscopy Ce3d spectra of Ce2O3 and CeO2

E Paparazzo - Journal of Physics: Condensed Matter, 2018 - iopscience.iop.org
X-ray photoemission spectroscopy (XPS) work on Ce 2 O 3 and CeO 2 oxides has been an
active topic of research over the past four decades or so. Such research aimed to find the …

Combined multiplet theory and experiment for the Fe 2p and 3p XPS of FeO and Fe2O3

PS Bagus, CJ Nelin, CR Brundle, BV Crist… - The Journal of …, 2021 - pubs.aip.org
The Al K alpha, 1486.6 eV, based x-ray photoelectron spectroscopy (XPS) of Fe 2p and Fe
3p for Fe (III) in Fe 2 O 3 and Fe (II) in FeO is compared with theoretical predictions based on …

Interpretation of XPS Mn(2p) spectra of Mn oxyhydroxides and constraints on the mechanism of MnO2 precipitation

HW Nesbitt, D Banerjee - American Mineralogist, 1998 - degruyter.com
Abstract Calculated Mn (2p3/2) X-ray photoelectron spectra (XPS) of Mn2+, Mn3+, and
Mn4+ free ions are strikingly similar to Mn (2p3/2) spectra of Mn2+-, Mn3+-, and Mn4+ …

[HTML][HTML] Aqueous electrochemical delithiation of cathode materials as a strategy to selectively recover lithium from waste lithium-ion batteries

PG Schiavi, AG Marrani, O Russina… - Journal of Energy …, 2024 - Elsevier
Lithium recovery from end-of-life Li-ion batteries (LIBs) through pyro-and hydrometallurgical
recycling processes involves several refining stages, with high consumption of reagents and …

Use of XPS to identify the oxidation state of Mn in solid surfaces of filtration media oxide samples from drinking water treatment plants

JM Cerrato, MF Hochella Jr, WR Knocke… - … science & technology, 2010 - ACS Publications
X-ray photoelectron spectroscopy (XPS) was used to identify Mn (II), Mn (III), and Mn (IV) in
the surfaces of pure oxide standards and filtration media samples from drinking water …

Chemical significance of x-ray photoelectron spectroscopy binding energy shifts: A Perspective

PS Bagus, CJ Nelin, CR Brundle - … of Vacuum Science & Technology A, 2023 - pubs.aip.org
The principal intent of this Perspective is to review the mechanisms that are responsible for
the shifts of binding energies, ΔBE, observed in x-ray photoelectron spectroscopy (XPS) …

[HTML][HTML] Analysis of the Fe 2p XPS for hematite α Fe2O3: Consequences of covalent bonding and orbital splittings on multiplet splittings

PS Bagus, CJ Nelin, CR Brundle, N Lahiri… - The Journal of …, 2020 - pubs.aip.org
The origins of the complex Fe 2p X-Ray Photoelectron Spectra (XPS) of hematite (α-Fe 2 O
3) are analyzed and related to the character of the bonding in this compound. This analysis …

Core-level satellites and outer core-level multiplet splitting in Mn model compounds

AJ Nelson, JG Reynolds, JW Roos - Journal of Vacuum Science & …, 2000 - pubs.aip.org
We report a systematic study of the Mn 2p, 3s, and 3p core-level photoemission and satellite
structures for Mn model compounds. Charge transfer from the ligand state to the 3d metal …

Extracting chemical information from XPS spectra: a perspective

PS Bagus, E Ilton, CJ Nelin - Catalysis Letters, 2018 - Springer
Important mechanisms that lead to features, often complex, in X-ray photoelectron
spectroscopy (XPS) spectra are defined and described. It is shown that there is much …