Deoxy-sugars often play a critical role in modulating the potency of many bioactive natural
products. Accordingly, there has been sustained interest in methods for their synthesis over …

Catalytic glycosylation has been a central reaction in carbohydrate chemistry since its
introduction by Fischer 125 years ago, but it is only in the past three to four decades that …

Recent developments in stereoselective 1, 2-cis glycosylation that have emerged during the
past decade are surveyed herein. For detailed coverage of the previous achievements in the …

With easily accessible and operator-friendly reagents, shelf-stable ortho-
methoxycarbonylethynylphenyl thioglycosides were efficiently prepared. Based on these …

The development of glycobiology relies on the sources of particular oligosaccharides in their
purest forms. As the isolation of the oligosaccharide structures from natural sources is not a …

Catalytic glycosylation is a vital transformation in synthetic carbohydrate chemistry due to its
ability to expediate the large-scale oligosaccharide synthesis for glycobiology studies with …

The methodological developments in gold (I)-and gold (III)-catalyzed glycosylation reactions
are fully surveyed, which exploit the special alkynophilicity or the Lewis acidity of the gold …

Visible‐light irradiation of 4‐p‐methoxyphenyl‐3‐butenylthioglucoside donors in the
presence of Umemoto's reagent and alcohol acceptors serves as a mild approach to O …

Au (I) in combination with AgOTf enables the unprecedented direct and α-stereoselective
catalytic synthesis of deoxyglycosides from glycals. Mechanistic investigations suggest that …

Deoxy sugars exist in numerous bioactive molecules and exert significant influences on their
physical, chemical, and biological properties. Due to the absence of directing group at C-2 …