Linear block copolymer synthesis

H Dau, GR Jones, E Tsogtgerel, D Nguyen… - Chemical …, 2022 - ACS Publications
Block copolymers form the basis of the most ubiquitous materials such as thermoplastic
elastomers, bridge interphases in polymer blends, and are fundamental for the development …

Precision polymer synthesis by controlled radical polymerization: Fusing the progress from polymer chemistry and reaction engineering

YN Zhou, JJ Li, TT Wang, YY Wu, ZH Luo - Progress in Polymer Science, 2022 - Elsevier
During the first 100 years of polymer science, controlled radical polymerization (also
recommended as reversible deactivation radical polymerization) is undoubtedly a …

Nitroxide-mediated polymerization

J Nicolas, Y Guillaneuf, C Lefay, D Bertin… - Progress in Polymer …, 2013 - Elsevier
Nitroxide-mediated polymerization (NMP) is a controlled/living radical polymerization
(CLRP) technique that enables the design of well-defined, functional and complex …

CO 2-responsive polymeric materials: synthesis, self-assembly, and functional applications

A Darabi, PG Jessop, MF Cunningham - Chemical Society Reviews, 2016 - pubs.rsc.org
CO2 is an ideal trigger for switchable or stimuli-responsive materials because it is benign,
inexpensive, green, abundant, and does not accumulate in the system. Many different CO2 …

Arresting elevated-temperature creep and achieving full cross-link density recovery in reprocessable polymer networks and network composites via nitroxide …

L Li, X Chen, K Jin, MB Rusayyis, JM Torkelson - Macromolecules, 2021 - ACS Publications
Thermosets and thermoset composites constitute an extraordinary challenge for recycling
and participation in a circular economy because their permanent covalent cross-links …

Nitroxide-mediated polymerization: a versatile tool for the engineering of next generation materials

HR Lamontagne, BH Lessard - ACS Applied Polymer Materials, 2020 - ACS Publications
Nitroxide-mediated polymerization (NMP) is a reversible-deactivation radical polymerization
technique (RDRP) that facilitates the synthesis of well-defined and complex macromolecular …

TEMPO in chemical transformations: from homogeneous to heterogeneous

HA Beejapur, Q Zhang, K Hu, L Zhu, J Wang… - ACS Catalysis, 2019 - ACS Publications
The organic nitroxyl radical, TEMPO (2, 2, 6, 6-tetramethylpiperidine-N-oxyl), finds a variety
of industrial applications for chemical transformations. Because of economic and …

The strength of multi-scale modeling to unveil the complexity of radical polymerization

DR D'hooge, PHM Van Steenberge… - Progress in Polymer …, 2016 - Elsevier
The strength of multi-scale modeling to support the fundamental understanding and design
of radical polymerization processes is illustrated, considering both controlled and free …

Dynamic Covalent Bond: Modes of Activation of the C—ON Bond in Alkoxyamines

G Audran, EG Bagryanskaya, R Bikanga… - Progress in Polymer …, 2023 - Elsevier
The materials of future depend a lot on properties that are due to “non stable” molecules.
Hence, Dynamic Covalent Bonds (DCB) are covalent bonds that are labile under specific …

Modification of polythiophene by the incorporation of processable polymeric chains: Recent progress in synthesis and applications

M Jaymand, M Hatamzadeh, Y Omidi - Progress in Polymer Science, 2015 - Elsevier
Intrinsically conductive polymers (ICPs) have attracted significant attention in recent
decades because of their wide range of potential applications in various fields such as …