Laboratory spectroscopy techniques to enable observations of interstellar ion chemistry

BA McGuire, O Asvany, S Brünken… - Nature Reviews …, 2020 - nature.com
Molecular ions have long been considered key intermediates in the evolution of molecular
complexity in the interstellar medium. However, owing to their reactivity and transient nature …

Millimeterwave and submillimeterwave laboratory spectroscopy in support of observational astronomy

SL Widicus Weaver - Annual Review of Astronomy and …, 2019 - annualreviews.org
The recent advancements in far-infrared (far-IR) astronomy brought about by the Herschel,
SOFIA, and ALMA observatories have led to technological advancements in millimeterwave …

ALMA detection of interstellar methoxymethanol (CH3OCH2OH)

BA McGuire, CN Shingledecker, ER Willis… - The Astrophysical …, 2017 - iopscience.iop.org
We report the detection of interstellar methoxymethanol (CH 3 OCH 2 OH) in Atacama Large
Millimeter/submillimeter Array (ALMA) Bands 6 and 7 toward the MM1 core in the high-mass …

Investigating the minimum energy principle in searches for new molecular species—The case of H2C3O isomers

RA Loomis, BA McGuire, C Shingledecker… - The Astrophysical …, 2015 - iopscience.iop.org
Recently, Lattelais et al. have interpreted aggregated observations of molecular isomers to
suggest that there exists a" minimum energy principle," such that molecular formation will …

Sublimation of laboratory ices millimeter/submillimeter experiment (SubLIME): Structure-specific identifications of products from UV-photolyzed methanol ice

KM Yocum, SN Milam, PA Gerakines… - The Astrophysical …, 2021 - iopscience.iop.org
Submillimeter/far-IR spectroscopy was used to detect and quantify organic molecules
sublimated after the ultraviolet photolysis (at 12 K) and warm-up (up to 300 K) of a methanol …

THz and mid-IR spectroscopy of interstellar ice analogs: methyl and carboxylic acid groups

S Ioppolo, BA McGuire, MA Allodi, GA Blake - Faraday discussions, 2014 - pubs.rsc.org
A fundamental problem in astrochemistry concerns the synthesis and survival of complex
organic molecules (COMs) throughout the process of star and planet formation. While it is …

Instrumentation for THz spectroscopy in the laboratory and in space

JC Pearson, BJ Drouin, S Yu - IEEE Journal of Microwaves, 2021 - ieeexplore.ieee.org
Spectroscopic measurements in the millimeter, submillimeter, or THz range, with resolutions
exceeding a MHz, provide for highly specific detections of gas-phase absorption and …

Rotational Spectrum and First Interstellar Detection of 2-methoxyethanol Using ALMA Observations of NGC 6334I

ZTP Fried, SJ El-Abd, BM Hays, G Wenzel… - The Astrophysical …, 2024 - iopscience.iop.org
We use both chirped-pulse Fourier transform and frequency-modulated absorption
spectroscopy to study the rotational spectrum of 2-methoxyethanol (CH 3 OCH 2 CH 2 OH) …

Weakly Bound Clusters in Astrochemistry? Millimeter and Submillimeter Spectroscopy of trans-HO3 and Comparison to Astronomical Observations

L Zou, BM Hays, SLW Weaver - The Journal of Physical Chemistry …, 2016 - ACS Publications
The emergence of chemical complexity during star and planet formation is largely guided by
the chemistry of unstable molecules that are reaction intermediates in terrestrial chemistry …

Rotational spectral studies of O (1D) insertion reactions with methane and ethylene: Methanol and vinyl alcohol in a supersonic expansion

BM Hays, N Wehres, BA DePrince, AAM Roy… - Chemical Physics …, 2015 - Elsevier
We report a new apparatus for millimeter/submillimeter spectroscopic studies of O (1 D)
insertion reactions to produce molecules of astrophysical interest. This study focuses on the …