Organometallic chemistry is one of the key assets to successfully achieve complex organic
transformations. Numerous tools have been conceived and developed to address problems …

The development of bulky monodentate alkoxide, chalcogenolate (ER, E= S, Se or Te),
amide, pnictide (ER2= N, P, As), alkyl, aryl and silyl ligands is briefly surveyed. These …

We report herein the synthesis, characterization, and coordination chemistry of a free N‐
aluminylene, namely a carbazolylaluminylene 2 b. This species is prepared via a reduction …

Aluminylenes (R− Al) are aluminium analogs of carbenes. In contrast to isolable carbenes,
aluminylenes are extremely rare species. In the past years, pioneered by Schnöckel, Roesky …

Low-coordinate cationic aluminum complexes are expected to be highly electrophilic and
therefore are of interest for Lewis acid catalysis, olefin polymerization, and other potential …

The search for extremely sterically demanding monodentate amide ligands to access main
group complexes in low-coordination numbers and highly reactive bonding modes is an …

A. Factors Favoring the Stability of Multiple Bonds to the Heavier Main Group 3 Elements
The chemistry of compounds that involve the heavier main group elements in multiple …

Here, we report an improved synthesis of the bulky phosphanide anion [P (Si i Pr3) 2]− in
synthetically useful yields and its complexation to group 12 metals. The ligand is obtained as …

Ultra‐wideline 27Al NMR experiments are conducted on coordination compounds with 27Al
nuclei possessing immense quadrupolar interactions that result from exceptionally …

Organoaluminum compounds have been explored widely owing to their importance in a
variety of applications, including organic syntheses and industrial catalytic processes.* 1 11 …