Crystal engineering: from molecule to crystal

GR Desiraju - Journal of the American Chemical Society, 2013 - ACS Publications
How do molecules aggregate in solution, and how do these aggregates consolidate
themselves in crystals? What is the relationship between the structure of a molecule and the …

The pi–halogen dimer (PHD) interaction: a versatile new construction unit for crystal engineering

R Bishop, ML Scudder, DC Craig… - … Crystals and Liquid …, 2005 - Taylor & Francis
The pi–halogen dimer (PHD) interaction is a new type of intermolecular packing motif
discovered in certain crystalline diquinoline compounds. It consists of a combination of one …

Friedländer annulation in the synthesis of azaheterocyclic compounds

M Shiri, MA Zolfigol, HG Kruger… - Advances in heterocyclic …, 2011 - Elsevier
Publisher Summary Since 1882, when Friedländer reported the synthesis of quinolines from
the condensation of o-aminoaryl carbonyl compounds and enolizable methylene groups …

Strength from weakness: The role of CH… N hydrogen bond in the formation of wave-like topology in crystals of aza-heterocycles

K Shivakumar, A Vidyasagar, A Naidu, RG Gonnade… - …, 2012 - pubs.rsc.org
Crystal engineering has succeeded in the design and construction of various architectures
such as tapes, ribbons, rosettes, layers etc. Though wavy layer packing is known to occur in …

Formation of infinite linear mercury metal chains assisted by face-to-face π− π (aryl− aryl) stacking interactions

JY Wu, HY Hsu, CC Chan, YS Wen… - Crystal Growth and …, 2009 - ACS Publications
Polymeric mercury compounds,[HgCl2 (bpym)] n (1, bpym= 5, 5′-bipyrimidine),[Hg2Br4
(bpym)] n (2), and [HgX2 (bpyz)] n (3-Cl, X= Cl; 3-Br, X= Br; bpyz= 2, 2′-bipyrazine), which …

Interplay of strong and weak hydrogen bonding in molecular complexes of some 4, 4′-disubstituted biphenyls with urea, thiourea and water

R Thaimattam, DS Reddy, F Xue, TCW Mak… - Journal of the …, 1998 - pubs.rsc.org
The crystal chemistry and engineering of a new family of host–guest complexes is
described. 4, 4′-Dicyanobiphenyl (DCBP) forms a 1: 1 complex, 1 with urea wherein the …

Role of Double C−H···N Weak Hydrogen Bonding Motifs in N-Heteroaromatic Inclusion Chemistry

SF Alshahateet, R Bishop, DC Craig… - Crystal growth & …, 2004 - ACS Publications
Dibromodiquinoline 8 forms lattice inclusion compounds when crystallized from solvents
such as dichloromethane, tetrahydrofuran, chloroform, and benzene. The crystal structures …

Banded ribbons of Cu 6 I 6 hexamers and multimodal thioether pyrazine ligands linked by self-complementary N⋯ H–C synthons

JJM Amoore, LR Hanton, MD Spicer - Dalton Transactions, 2003 - pubs.rsc.org
The multimodal coordinating ability of a new thioether pyrazine ligand was used in
conjunction with CuI to construct one-dimensional banded ribbons containing Cu6I6 …

Dimeric C–H⋯ N interactions and the crystal engineering of new inclusion host molecules

SF Alshahateet, R Bishop, DC Craig, ML Scudder - CrystEngComm, 2001 - pubs.rsc.org
Single crystal X-ray studies of (6)·(tetrahydrofuran) 2 and (6)·(benzene) 1.5 reveal the
presence of two distinct types of dimeric edge–edge C–H⋯ N packing motifs. All of the …

Design and Synthesis of a C2-Symmetric Self-Complementary Hydrogen-Bonding Cleft Molecule Based on the Bicyclo[3.3.1]nonane and 4-Oxo-5-azaindole …

S Stoncius, E Butkus, A Žilinskas… - The Journal of …, 2004 - ACS Publications
The synthesis of a C 2-symmetric cleft molecule 2 based on the fused framework between
bicyclo [3.3. 1] nonane and 4-oxo-5-azaindole, incorporating a self-complementary …