Shining new light on biological systems: luminescent transition metal complexes for bioimaging and biosensing applications

LCC Lee, KKW Lo - Chemical Reviews, 2024 - ACS Publications
Luminescence imaging is a powerful and versatile technique for investigating cell
physiology and pathology in living systems, making significant contributions to life science …

Light-Emitting Self-Assembled Materials Based on d8 and d10 Transition Metal Complexes

VWW Yam, VKM Au, SYL Leung - Chemical reviews, 2015 - ACS Publications
The spontaneous self-organization of matters has always been one of the most fascinating
wonders in the world. Self-assembly refers to “the autonomous organization of components …

Cyclic (alkyl)-and (aryl)-(amino) carbene coinage metal complexes and their applications

R Jazzar, M Soleilhavoup, G Bertrand - Chemical reviews, 2020 - ACS Publications
Cyclic (alkyl)-and (aryl)-(amino) carbenes (CAACs and CAArCs) are stronger σ-donors and
π-acceptors than imidazol-2-ylidenes and imidazolidin-2-ylidenes, the well-known N …

Highly phosphorescent platinum (II) emitters: photophysics, materials and biological applications

K Li, GSM Tong, Q Wan, G Cheng, WY Tong… - Chemical …, 2016 - pubs.rsc.org
In recent years a blossoming interest in the synthesis, photophysics and application of
phosphorescent Pt (II) complexes, particularly on their uses in bioimaging, photocatalysis …

Main avenues in gold coordination chemistry

RP Herrera, MC Gimeno - Chemical Reviews, 2021 - ACS Publications
In this contribution, we provide an overview of the main avenues that have emerged in gold
coordination chemistry during the last years. The unique properties of gold have motivated …

Dual gold catalysis

ASK Hashmi - Accounts of Chemical Research, 2014 - ACS Publications
For more than a decade the innovative field of homogeneous catalysis by gold was
dominated by the interaction of the substrate molecule with one gold center, in most cases in …

When self-assembly meets biology: luminescent platinum complexes for imaging applications

M Mauro, A Aliprandi, D Septiadi, NS Kehr… - Chemical Society …, 2014 - pubs.rsc.org
Luminescent platinum complexes have attractive chemical and photophysical properties
such as high stability, emission in the visible region, high emission quantum yields and long …

Gold carbenes, gold-stabilized carbocations, and cationic intermediates relevant to gold-catalysed enyne cycloaddition

RJ Harris, RA Widenhoefer - Chemical Society Reviews, 2016 - pubs.rsc.org
Cationic gold complexes in which gold is bound to a formally divalent carbon atom, typically
formulated as gold carbenes or α-metallocarbenium ions, have been widely invoked in a …

Intriguing mechanistic labyrinths in gold (I) catalysis

C Obradors, AM Echavarren - Chemical Communications, 2014 - pubs.rsc.org
Many mechanistically intriguing reactions have been developed in the last decade using
gold (I) as catalyst. Here we review the main mechanistic proposals in gold-catalysed …

Cyclometalated gold (III) complexes: synthesis, reactivity, and physicochemical properties

R Kumar, C Nevado - Angewandte Chemie International …, 2017 - Wiley Online Library
This Review showcases the ability of bi‐and tridentate ligands to stabilize gold in high
oxidation states through the formation of mono‐and biscyclometalated gold (III) complexes …