Molecular catalysts for water oxidation

JD Blakemore, RH Crabtree, GW Brudvig - Chemical Reviews, 2015 - ACS Publications
The development of technologies for the production of chemical fuels or useful compounds
with renewable energy (eg, sunlight) and inexpensive feedstocks relies on an abundant …

[HTML][HTML] Artificial photosynthesis: molecular systems for catalytic water oxidation

MD Karkas, O Verho, EV Johnston… - Chemical reviews, 2014 - ACS Publications
The sustainable production of clean energy constitutes one of the most important scientific
challenges of the 21st century. Currently, the major part of the global energy supply is …

Insights into the pollutant electron property inducing the transformation of peroxymonosulfate activation mechanisms on manganese dioxide

R Huang, P Gao, J Zhu, Y Zhang, Y Chen… - Applied Catalysis B …, 2022 - Elsevier
Herein, using manganese dioxide octahedral molecular sieve (Mn-OMS) as the catalyst, we
investigate how pollutant electron property affects the peroxymonosulfate (PMS) activation …

Molecular catalysis of electrochemical reactions. Mechanistic aspects

JM Savéant - Chemical Reviews, 2008 - ACS Publications
Electrochemical reactions often require an important overpotential1 to proceed at an
appreciable rate. This is particularly true when the reaction does not merely consist of an …

Water oxidation using earth-abundant transition metal catalysts: opportunities and challenges

MD Kärkäs, B Åkermark - Dalton Transactions, 2016 - pubs.rsc.org
Catalysts for the oxidation of H2O are an integral component of solar energy to fuel
conversion technologies. Although catalysts based on scarce and precious metals have …

Half-sandwich iridium complexes for homogeneous water-oxidation catalysis

JD Blakemore, ND Schley, D Balcells… - Journal of the …, 2010 - ACS Publications
Iridium half-sandwich complexes of the types Cp* Ir (N− C) X,[Cp* Ir (N− N) X] X, and [CpIr
(N− N) X] X are catalyst precursors for the homogeneous oxidation of water to dioxygen …

Calcium Manganese(III) Oxides (CaMn2O4x H2O) as Biomimetic Oxygen‐Evolving Catalysts

MM Najafpour, T Ehrenberg, M Wiechen… - Angewandte Chemie …, 2010 - infona.pl
Biomimetic and efficient: Mixed calcium manganese (III) oxides (see structure; Ca green, Mn
red, O white) with elemental compositions and structures mimicking the active site of …

Comparison of primary oxidants for water-oxidation catalysis

AR Parent, RH Crabtree, GW Brudvig - Chemical Society Reviews, 2013 - pubs.rsc.org
Comparison of primary oxidants for water-oxidation catalysis - Chemical Society Reviews (RSC
Publishing) DOI:10.1039/C2CS35225G Royal Society of Chemistry View PDF VersionPrevious …

Functional models for the oxygen-evolving complex of photosystem II

CW Cady, RH Crabtree, GW Brudvig - Coordination chemistry reviews, 2008 - Elsevier
In the last 10 years, a number of advances have been made in the study of the oxygen-
evolving complex (OEC) of photosystem II (PSII). Along with this new understanding of the …

Synthetic manganese–calcium oxides mimic the water-oxidizing complex of photosynthesis functionally and structurally

I Zaharieva, MM Najafpour, M Wiechen… - Energy & …, 2011 - pubs.rsc.org
In the worldwide search for sustainable energy technologies, water oxidation by abundant
low-cost materials is of key importance. In nature, this process is efficiently catalyzed by an …