The enzymatic synthesis of esters and peptides is unfavoured in aqueous solvent systems
due to competing hydrolysis. This can be overcome by using energy rich substrate …

This comprehensive review summarizes the published literature data concerning the
intramolecular Diels–Alder reactions of vinylarenes (the IMDAV reaction) and alkynyl arenes …

The asymmetric induction afforded by a chiral sulfinyl group in a palladium/Brønsted-acid-
catalyzed intramolecular allylic amination was investigated. Predictions of the …

For the first time, the transformation of biobased 5-HMF derivatives succeeded in a 2×[4+ 2]
cascade cycloaddition reaction, leading to a drastic (3–5-fold) increase in molecular …

3-(Thien-2-yl)-and 3-(thien-3-yl) allylamines, readily accessible from the corresponding
thienyl aldehydes, can interact with a broad range of anhydrides and α, β-unsaturated acids …

Abstract The class of Double Diels‐Alder (DDA) reactions leading the targets concisely
where numerous synthetic pursuits have been rewarded with conceptually novel and …

In the title compound, C25H25NO7S, the molecular conformation is stabilized by
intramolecular O—H⋯ O and N—H⋯ O hydrogen bonds, which form S (6) and S (8) ring …

Regioselective metal insertion into aromatic C–C bonds is a long-standing problem critical
for development of new arene functionalizations and cleaner conversion of fossil fuel into …

In the title compound, C23H17N3O9S2, C—H⋯ O hydrogen bonds link adjacent molecules
in a three-dimensional network, while π–π stacking interactions, with centroid–centroid …

A series of 1, 4: 5, 8-diepoxynaphthalenes, annellated with six-membered carbo-and
heterocycles, was obtained via the intramolecular Diels–Alder furan (IMDAF) cycloaddition …