The functionalization of coordinated dinitrogen to form nitrogen–element bonds en route to
nitrogen-containing molecules is a long-standing challenge in chemical synthesis. The …

Activation of dinitrogen plays an important role in daily anthropogenic life, and the processes
by which this fixation occurs have been a longstanding and significant research focus within …

Since the mid 2000's, the incorporation of Lewis acid moieties in ligands for transition metals
has been studied extensively. So-called ambiphilic ligands were shown to possess rich and …

This third review in a series involving reactions of hydrosilanes and transition metal
complexes and characterization of the products covers the period 2009 thru 2013. After a …

Nitrogenases are the enzymes by which certain microorganisms convert atmospheric
dinitrogen (N2) to ammonia, thereby providing essential nitrogen atoms for higher …

A series of dinitrogen-bridged dimolybdenum–dinitrogen complexes bearing 4-substituted
PNP-pincer ligands are synthesized by the reduction of the corresponding molybdenum …

Names: Stradiotto, Mark, author.| Lundgren, Rylan, author. Title: Ligand design in metal
chemistry: reactivity and catalysis/[edited by] Mark Stradiotto, Rylan Lundgren. Description …

Isolation of key intermediate complexes in dinitrogen functionalization is crucial for
elucidating the mechanistic details and further investigation. Herein, the synthesis and …

Dinitrogen (N2) is the most abundant gas in Earth's atmosphere, but its inertness hinders its
use as a nitrogen source in the biosphere and in industry. Efficient catalysts are hence …

Conspectus The iron–molybdenum cofactor of nitrogenase has unprecedented coordination
chemistry, including a high-spin iron cluster called the iron-molybdenum cofactor (FeMoco) …