3d transition metals for C–H activation

P Gandeepan, T Müller, D Zell, G Cera… - Chemical …, 2018 - ACS Publications
C–H activation has surfaced as an increasingly powerful tool for molecular sciences, with
notable applications to material sciences, crop protection, drug discovery, and …

[HTML][HTML] A comprehensive overview of directing groups applied in metal-catalysed C–H functionalisation chemistry

C Sambiagio, D Schönbauer, R Blieck… - Chemical Society …, 2018 - pubs.rsc.org
The present review is devoted to summarizing the recent advances (2015–2017) in the field
of metal-catalysed group-directed C–H functionalisation. In order to clearly showcase the …

Catalytic transformations of functionalized cyclic organic carbonates

W Guo, JE Gómez, À Cristòfol, J Xie… - Angewandte Chemie …, 2018 - Wiley Online Library
Functionalized cyclic organic carbonates and related heterocycles have emerged as highly
versatile heterocyclic substrates for ring‐opening and decarboxylative catalytic …

Inert C–H bond transformations enabled by organometallic manganese catalysis

Y Hu, B Zhou, C Wang - Accounts of Chemical Research, 2018 - ACS Publications
Conspectus Traditional organic synthesis relies heavily on the transformations of various
preinstalled functional groups, such as cross-coupling reactions using organohalides and …

Flow rhodaelectro-catalyzed alkyne annulations by versatile C–H activation: mechanistic support for rhodium (III/IV)

WJ Kong, LH Finger, AM Messinis… - Journal of the …, 2019 - ACS Publications
A flow-metallaelectro-catalyzed C–H activation was realized in terms of robust rhodaelectro-
catalyzed alkyne annulations. To this end, a modular electro-flow cell with a porous graphite …

[HTML][HTML] Green strategies for transition metal-catalyzed C–H activation in molecular syntheses

U Dhawa, N Kaplaneris, L Ackermann - Organic Chemistry Frontiers, 2021 - pubs.rsc.org
Transition metal catalyzed C–H activation has surfaced as a powerful tool to improve the
efficacy of molecular synthesis. Last two decades have witnessed a considerable progress …

Rhodaelectro-Catalyzed C–H and C–C Activation

Y Qiu, C Zhu, M Stangier, J Struwe… - CCS …, 2021 - chinesechemsoc.org
Rhodium (III) catalysis has set the stage for a plethora of oxidative C–H functionalizations
over the last decade, which have predominantly employed stoichiometric amounts of toxic …

C–H functionalization reactions under flow conditions

S Santoro, F Ferlin, L Ackermann… - Chemical Society Reviews, 2019 - pubs.rsc.org
C–H functionalization technologies have progressed enormously in the last decade as
testified by the great number of publications that have appeared in the literature, which are …

[HTML][HTML] Pushing the boundaries of C–H bond functionalization chemistry using flow technology

S Govaerts, A Nyuchev, T Noel - Journal of Flow Chemistry, 2020 - Springer
C–H functionalization chemistry is one of the most vibrant research areas within synthetic
organic chemistry. While most researchers focus on the development of small-scale batch …

Late‐Stage Diversification through Manganese‐Catalyzed C− H Activation: Access to Acyclic, Hybrid, and Stapled Peptides

N Kaplaneris, T Rogge, R Yin, H Wang… - Angewandte …, 2019 - Wiley Online Library
Bioorthogonal C− H allylation with ample scope was accomplished through a versatile
manganese (I)‐catalyzed C− H activation for the late‐stage diversification of structurally …