Intermediates, isolation and mechanistic insights into zinc hydride-catalyzed 1, 2-regioselective hydrofunctionalization of N-heteroarenes
The conjugated bis-guanidinate-supported zinc hydride [{LZnH} 2; L={(ArHN)(ArN)–C═ N–
C═(NAr)(NHAr); Ar= 2, 6-Et2-C6H3}](I)-catalyzed highly demanding exclusive 1, 2 …
C═(NAr)(NHAr); Ar= 2, 6-Et2-C6H3}](I)-catalyzed highly demanding exclusive 1, 2 …
Zinc-Catalyzed Chemoselective Reduction of Nitriles to N-Silylimines through Hydrosilylation: Insights into the Reaction Mechanism
RK Sahoo, S Nembenna - Inorganic Chemistry, 2023 - ACS Publications
The N, N′-chelated conjugated bis-guanidinate (CBG) supported zinc hydride (Zn-1) pre-
catalyzed highly challenging chemoselective mono-hydrosilylation of a wide range of nitriles …
catalyzed highly challenging chemoselective mono-hydrosilylation of a wide range of nitriles …
Zinc Catalyzed Hydroelementation (HE; E= B, C, N, and O) of Carbodiimides: Intermediates Isolation and Mechanistic Insights
The conjugated bis-guanidinate (CBG) supported zinc hydride,[{LZnH} 2; L={(ArHN)(ArN)-
C═ N–C═(NAr)(NHAr); Ar= 2, 6-Et2-C6H3}](1)(pre)-catalyzed addition of E–H (E= B, C, N …
C═ N–C═(NAr)(NHAr); Ar= 2, 6-Et2-C6H3}](1)(pre)-catalyzed addition of E–H (E= B, C, N …
Zinc Hydride-Catalyzed Dihydroboration of Isonitriles and Nitriles: Mechanistic Studies with the Structurally Characterized Zinc Intermediates
The conjugated bis-guanidinate (CBG)-stabilized zinc hydride,[{LZnH} 2;(L={(ArNH)(ArN)–
C═ N–C═(NAr)(NHAr)}; Ar= 2, 6-Et2-C6H3)](Zn-1), is shown to be a highly active catalyst …
C═ N–C═(NAr)(NHAr)}; Ar= 2, 6-Et2-C6H3)](Zn-1), is shown to be a highly active catalyst …
Comparison of Two Zinc Hydride Precatalysts for Selective Dehydrogenative Borylation of Terminal Alkynes: A Detailed Mechanistic Study
The conjugated bis-guanidinate-stabilized zinc hydride complex (I)-precatalyzed
chemoselective dehydroborylation of a wide array of terminal alkynes with excellent yields is …
chemoselective dehydroborylation of a wide array of terminal alkynes with excellent yields is …
Organoaluminum Catalyzed Guanylation and Hydroboration Reactions of Carbodiimides
Herein, we report the guanylation of carbodiimides with primary and secondary alkyl/aryl
amines and the reduction of CDIs via hydroboration using molecular conjugated bis …
amines and the reduction of CDIs via hydroboration using molecular conjugated bis …
Zinc hydride catalyzed hydroboration of esters
AG Patro, RK Sahoo, S Nembenna - Dalton Transactions, 2024 - pubs.rsc.org
The conjugated bis-guanidinate (CBG)-supported zinc hydride {LZnH} 2; L={(ArHN)(ArN)–
CN–C (NAr)(NHAr); Ar= 2, 6-Et2-C6H3}(I) is utilized as a catalyst for the hydroboration of …
CN–C (NAr)(NHAr); Ar= 2, 6-Et2-C6H3}(I) is utilized as a catalyst for the hydroboration of …
Aluminum-catalyzed selective hydroboration of carbonyls and dehydrocoupling of alcohols, phenols, amines, thiol, selenol, silanols with HBpin
Abstract A popular N, N'-chelated NacNac analogue, ie., conjugated bis-guanidinate (CBG)
stabilized aluminum dihydride LAlH 2 (1)[L={(ArHN)(ArN)–Cdouble bondN–C=(NAr)(NHAr)}; …
stabilized aluminum dihydride LAlH 2 (1)[L={(ArHN)(ArN)–Cdouble bondN–C=(NAr)(NHAr)}; …
Germanium Hydride Catalyzed Selective Hydroboration and Cyanosilylation of Ketones
AP Khuntia, N Sarkar, AG Patro… - European Journal of …, 2022 - Wiley Online Library
Two new examples of β‐diketiminate or NacNac analogues, ie, conjugated bis‐guanidinate
(CBG) stabilized low valent germanium chloride (1) and germanium hydride (2) complexes …
(CBG) stabilized low valent germanium chloride (1) and germanium hydride (2) complexes …
Insights Into the Magnesium‐Catalyzed C− C Coupling of Terminal Alkynes with Carbodiimides
The bis‐guanidinate anion stabilized amido magnesium (II) compound [LMgN (SiMe3) 2;
L={(ArHN)(ArN)− C= N− C=(NAr)(NHAr); Ar= 2, 6‐Et2− C6H3}](Mg‐1) has been synthesized …
L={(ArHN)(ArN)− C= N− C=(NAr)(NHAr); Ar= 2, 6‐Et2− C6H3}](Mg‐1) has been synthesized …