Filling the gap between the quantum and classical worlds of nanoscale magnetism: giant molecular aggregates based on paramagnetic 3d metal ions

C Papatriantafyllopoulou, EE Moushi… - Chemical Society …, 2016 - pubs.rsc.org
In this review, aspects of the syntheses, structures and magnetic properties of giant 3d and
3d/4f paramagnetic metal clusters in moderate oxidation states are discussed. The term …

Cluster-based single-molecule magnets

CJ Milios, REP Winpenny - Molecular Nanomagnets and Related …, 2015 - Springer
This review covers single-molecule magnets, not only focussing on developments since
2005 but also including coverage of earlier work where necessary for understanding of …

Hierarchical Assembly of a {MnII15MnIII4} Brucite Disc: Step-by-Step Formation and Ferrimagnetism

YK Deng, HF Su, JH Xu, WG Wang… - Journal of the …, 2016 - ACS Publications
In search of functional molecular materials and the study of their formation mechanism, we
report the elucidation of a hierarchical step-by-step formation from monomer (Mn) to …

Hexadecacobalt (II)‐containing polyoxometalate‐based single‐molecule magnet

M Ibrahim, Y Lan, BS Bassil, Y Xiang… - Angewandte Chemie …, 2011 - Wiley Online Library
Polyoxometalates (POMs) are a remarkable class of inorganic compounds with enormous
structural and compositional diversity and potential applications in various fields, such as …

Bulk assembly of multicomponent zero-dimensional metal halides with dual emission

C Zhou, S Lee, H Lin, J Neu, M Chaaban… - ACS Materials …, 2020 - ACS Publications
Bulk assemblies of zero-dimensional (0D) metal halides with exceptional structural
versatility have enabled the development of a number of highly efficient emitters with tunable …

Beyond clusters: supramolecular networks self‐assembled from nanosized silver clusters and inorganic anions

Z Wang, XY Li, LW Liu, SQ Yu, ZY Feng… - … A European Journal, 2016 - Wiley Online Library
Assembly of small clusters into rigid bodies with precise shape and symmetry has been
witnessed by the significant advances in cluster‐based metal–organic frameworks (MOFs) …

Accurate binding of porous aluminum molecular ring catalysts with the substrate

D Luo, H Xiao, MY Zhang, SD Li, L He, H Lv, CS Li… - Chemical …, 2023 - pubs.rsc.org
Metal molecular rings are a class of compounds with aesthetically pleasing symmetry and
fundamentally useful properties. The reported work generally focuses on the ring center …

Substitution effects regulate the formation of butterfly-shaped tetranuclear Dy (III) cluster and Dy-based hydrogen-bonded helix frameworks: structure and magnetic …

ZH Zhu, HF Wang, S Yu, HH Zou, HL Wang… - Inorganic …, 2020 - ACS Publications
The generation of two types of complexes with different topological connections and
completely different structural types merely via the substitution effect is extremely rare …

Transition Metal Single-Molecule Magnets: A {Mn31} Nanosized Cluster with a Large Energy Barrier of ∼60 K and Magnetic Hysteresis at ∼5 K

P Abbasi, K Quinn, DI Alexandropoulos… - Journal of the …, 2017 - ACS Publications
The first {Mn31} cluster (1) has been prepared from carboxylate ions and the
chelating/bridging ligand α-methyl-2-pyridine-methanol. Compound 1 possesses a unique …

A single-stranded {Gd 18} nanowheel with a symmetric polydentate diacylhydrazone ligand

K Wang, ZL Chen, HH Zou, K Hu, HY Li… - Chemical …, 2016 - pubs.rsc.org
An unprecedented {Gd18} nanowheel was solvothermally synthesized with a novel
diacylhydrazone ligand. It features a rare single-stranded skeleton just like a Reuleaux …