Donor and donor–donor carbenes are two important kinds of carbenes, which have
experienced tremendous growth in the past two decades. This review provides a …

This review covers the addition of diazo compounds to ketones to afford homologated
ketones, either in the presence or in the absence of promoters or catalysts. Reactions with …

Catalytic Asymmetric Synthesis Seminal text presenting detailed accounts of the most
important catalytic asymmetric reactions known today This book covers the preparation of …

The discovery and development of new chemical reactions is a major focus of research
activity in organic chemistry. The chemical synthesis of molecules provided by Nature has …

Carbenes, thought of only as transient species for a long time, have become ubiquitous in
organometallic chemistry. Their interaction with a metal center, which allows for their …

The synthetic uses of organicdiazo compounds for carbenoid transformations have
undergone a renais-sance in recent years as a result of the development of new transition …

Conspectus Fluorine-containing cyclopropanes are a subclass of cyclopropane derivatives
that have generated considerable interest in medicinal chemistry for several decades. The …

A triphenylphosphinegold (I)-catalyzed cyclopropanation of olefins using propargyl esters as
gold (I)− carbene precursors is reported. This reaction provided the basis for the use of a …

The metal‐catalyzed decomposition of diazo compounds in the presence of alkenes is a
well‐established reaction. Since the original Organic Reactions review on the reaction of …

The transition metal catalyzed reaction of α‐diazo carbonyl compounds has found numerous
applications in organic synthesis, and its use in either heterocyclic or carbocyclic ring …