Molecular reactions at aqueous interfaces

MF Ruiz-Lopez, JS Francisco… - Nature Reviews …, 2020 - nature.com
This Review aims to critically analyse the emerging field of chemical reactivity at aqueous
interfaces. The subject has evolved rapidly since the discovery of the so-called 'on-water …

Protons and hydroxide ions in aqueous systems

N Agmon, HJ Bakker, RK Campen… - Chemical …, 2016 - ACS Publications
Understanding the structure and dynamics of water's constituent ions, proton and hydroxide,
has been a subject of numerous experimental and theoretical studies over the last century …

Photoinduced oxidation reactions at the air–water interface

JM Anglada, MTC Martins-Costa… - Journal of the …, 2020 - ACS Publications
Chemistry on water is a fascinating area of research. The surface of water and the interfaces
between water and air or hydrophobic media represent asymmetric environments with …

Ions at interfaces: the central role of hydration and hydrophobicity

D Bastos-González, L Pérez-Fuentes… - Current opinion in …, 2016 - Elsevier
It is increasingly being accepted that solvation properties of ions and interfaces (hydration of
ions, hydrophobic or hydrophilic character of interfaces) play a fundamental role in ion …

Interactions between polyelectrolyte brushes and Hofmeister ions: chaotropes versus kosmotropes

R Kou, J Zhang, T Wang, G Liu - Langmuir, 2015 - ACS Publications
We have investigated the interactions between the positively charged poly [2-
(methacryloyloxy) ethyltrimethylammonium chloride](PMETAC) brushes and the Hofmeister …

Ion-specific and thermal effects in the stabilization of the gas nanobubble phase in bulk aqueous electrolyte solutions

SO Yurchenko, AV Shkirin, BW Ninham, AA Sychev… - Langmuir, 2016 - ACS Publications
Ion-stabilized nanobubbles in bulk aqueous solutions of various electrolytes were
investigated. To understand the ion-specific mechanism of nanobubble stabilization, an …

On the mechanisms of ion adsorption to aqueous interfaces: air-water vs. oil-water

SW Devlin, I Benjamin… - Proceedings of the …, 2022 - National Acad Sciences
The adsorption of ions to water-hydrophobe interfaces influences a wide range of
phenomena, including chemical reaction rates, ion transport across biological membranes …

Interactions between monovalent cations and polyethylene glycol: A study at micro level

M Yu, X Kang, L Qian - Colloids and Surfaces A: Physicochemical and …, 2024 - Elsevier
Understanding the intricate interplay between ions and polymers holds key implications for a
myriad of fields, from biomedicine to materials science. Here, we present a comprehensive …

Central role of bicarbonate anions in charging water/hydrophobic interfaces

X Yan, M Delgado, J Aubry, O Gribelin… - The Journal of …, 2018 - ACS Publications
Aqueous interfaces are ubiquitous in Nature and play a fundamental role in environmental
or biological processes or modern nanotechnologies. These interfaces are negatively …

Frequency and field-dependent response of confined electrolytes from Brownian dynamics simulations

G Stoltz, B Rotenberg - The Journal of Chemical Physics, 2023 - pubs.aip.org
Using Brownian dynamics simulations, we investigate the effects of confinement, adsorption
on surfaces, and ion–ion interactions on the response of confined electrolyte solutions to …