Photoactive Metal-to-Ligand Charge Transfer Excited States in 3d6 Complexes with Cr0, MnI, FeII, and CoIII

N Sinha, OS Wenger - Journal of the American Chemical Society, 2023 - ACS Publications
Many coordination complexes and organometallic compounds with the 4d6 and 5d6
valence electron configurations have outstanding photophysical and photochemical …

Recent advances in organic luminescent materials with narrowband emission

JM Ha, SH Hur, A Pathak, JE Jeong, HY Woo - NPG Asia Materials, 2021 - nature.com
Abstract The International Telecommunication Union announced a new color gamut
standard of broadcast service television (BT 2020) for ultra-high-definition TV in 2012. To …

Luminescent Complexes of Platinum, Iridium, and Coinage Metals Containing N-Heterocyclic Carbene Ligands: Design, Structural Diversity, and Photophysical …

H Amouri - Chemical Reviews, 2022 - ACS Publications
The employment of N-heterocyclic carbenes (NHCs) to design luminescent metal
compounds has been the focus of recent intense investigations because of the strong σ …

Luminescent first-row transition metal complexes

C Wegeberg, OS Wenger - Jacs Au, 2021 - ACS Publications
Precious and rare elements have traditionally dominated inorganic photophysics and
photochemistry, but now we are witnessing a paradigm shift toward cheaper and more …

Nanoengineering triplet–triplet annihilation upconversion: from materials to real-world applications

T Schloemer, P Narayanan, Q Zhou, E Belliveau… - ACS …, 2023 - ACS Publications
Using light to control matter has captured the imagination of scientists for generations, as
there is an abundance of photons at our disposal. Yet delivering photons beyond the surface …

Pyrene-based metal organic frameworks: from synthesis to applications

FP Kinik, A Ortega-Guerrero, D Ongari… - Chemical Society …, 2021 - pubs.rsc.org
Pyrene is one of the most widely investigated aromatic hydrocarbons given to its unique
optical and electronic properties. Hence, pyrene-based ligands have been attractive for the …

Charge‐transfer and spin‐flip states: Thriving as complements

WR Kitzmann, K Heinze - Angewandte Chemie International …, 2023 - Wiley Online Library
Transition metal complexes with photoactive charge‐transfer excited states are pervasive
throughout the literature. In particular,[Ru (bpy) 3] 2+(bpy= 2, 2′‐bipyridine), with its metal …

Phosphorescent organic light-emitting devices: Iridium based emitter materials–An overview

J Jayabharathi, V Thanikachalam… - Coordination Chemistry …, 2023 - Elsevier
This review presents an efficient phosphorescent organic light-emitting diodes (PhOLEDs)
based on Ir (III) complexes with low cost fabrication process. Because of excellent charge …

Pyrene-Decoration of a Chromium(0) Tris(diisocyanide) Enhances Excited State Delocalization: A Strategy to Improve the Photoluminescence of 3d6 Metal …

C Wegeberg, D Häussinger… - Journal of the American …, 2021 - ACS Publications
There is a long-standing interest in iron (II) complexes that emit from metal-to-ligand charge
transfer (MLCT) excited states, analogous to ruthenium (II) polypyridines. The 3d6 electrons …

Metal–Organic Bichromophore Lowers the Upconversion Excitation Power Threshold and Promotes UV Photoreactions

H Li, C Wang, F Glaser, N Sinha… - Journal of the American …, 2023 - ACS Publications
Sensitized triplet–triplet annihilation upconversion is a promising strategy to use visible light
for chemical reactions requiring the energy input of UV photons. This strategy avoids unsafe …