Photoelectron spectroscopy has long been a powerful method in the toolbox of experimental
physical chemistry and molecular physics. Recent improvements in coincidence methods …

Clean combustion, ie, the reduction of NOx and soot emissions, and carbon neutrality,
achieved in part by biofuel synthesis, are major milestones in the transition to a sustainable …

The electronic structure of biradicals is characterized by the presence of two unpaired
electrons in degenerate or near‐degenerate molecular orbitals. In particular, some of the …

We have investigated the reaction between 2-methylallyl radicals and oxygen molecules
with experimental and computational methods. Kinetic experiments were conducted in a …

We have used laser-photolysis–photoionization mass spectrometry, quantum chemical
calculations, and master equation simulations to investigate the kinetics of the reaction …

Di-isobutylene has received significant attention as a promising fuel blendstock, as it can be
synthesized via biological routes and is a short-listed molecule from the Co-Optima initiative …

The resonance-stabilized 2-methylallyl radical, 2-MA, is considered as a possible
intermediate in the formation of polycyclic aromatic hydrocarbons (PAHs) in combustion …

Abstract Oxalyl chloride,(ClCO) 2 (ClCO)_2, is widely used as a photolytic source of Cl
atoms in reaction kinetics studies.(ClCO) 2 (ClCO)_2 photolysis is typically assumed to …

Trimethylborane (TMB) and its chemistry upon pyrolysis have been investigated by
threshold photoelectron spectroscopy. TMB shows an unstructured spectrum and its …

A new feature was recently implemented in the MESMER program, a master equation code,
which permits the user to directly use to experimental kinetic traces in parameter …