Palladium complexes of N‐heterocyclic carbenes as catalysts for cross‐coupling reactions—A synthetic chemist's perspective

EAB Kantchev, CJ O'Brien… - Angewandte Chemie …, 2007 - Wiley Online Library
Abstract Palladium‐catalyzed C C and C N bond‐forming reactions are among the most
versatile and powerful synthetic methods. For the last 15 years, N‐heterocyclic carbenes …

Aus der Sicht des Synthetikers: Palladiumkomplexe N‐heterocyclischer Carbene als Katalysatoren für Kreuzkupplungen

EAB Kantchev, CJ O'Brien, MG Organ - Angewandte Chemie, 2007 - Wiley Online Library
Abstract Palladiumkatalysierte C‐C‐und C‐N‐Kupplungen zählen zu den vielseitigsten und
leistungsfähigsten Syntheseverfahren. Seit 15 Jahren erfreuen sich die N‐heterocyclischen …

Functionalized imidazolium salts for task-specific ionic liquids and their applications

S Lee - Chemical Communications, 2006 - pubs.rsc.org
Recent developments in task specifically functionalized imidazolium salts, which can be
used for specific tasks ranging from catalysts recycling, supports for organic synthesis …

Donor‐functionalised n‐heterocyclic carbene complexes of Group 9 and 10 metals in catalysis: Trends and directions

AT Normand, KJ Cavell - European Journal of Inorganic …, 2008 - Wiley Online Library
This review focuses on the latest advances in homogeneous catalysis with donor‐
functionalised (donor= C, N, O, S or P) N‐heterocyclic carbene complexes of group 9 and 10 …

Stereochemical and structural characteristics of single-and double-site Pd (II)–N-heterocyclic carbene complexes: Promising catalysts in organic syntheses ranging …

S Budagumpi, RA Haque, AW Salman - Coordination Chemistry Reviews, 2012 - Elsevier
This review discusses the principles underlying the design, synthesis, and catalytic
application of mono-and binuclear Pd (II)–N-heterocyclic carbene (NHC) complexes. The …

Synthesis of palladium and platinum complexes with phosphine-functionalized benzimidazolin-2-ylidene ligands

FE Hahn, MC Jahnke, T Pape - Organometallics, 2006 - ACS Publications
Phosphine-functionalized benzimidazolium salts of the type N-(2-phosphinoethyl)-N '-
alkylbenzimidazolium chloride (4, alkyl= ethyl; 5, alkyl= n-propyl; 6, alkyl= n-butyl) and N, N ' …

Nickel (II) Complexes of Bidentate N‐Heterocyclic Carbene/Phosphine Ligands: Efficient Catalysts for Suzuki Coupling of Aryl Chlorides

CC Lee, WC Ke, KT Chan, CL Lai… - … –A European Journal, 2007 - Wiley Online Library
Nickel (II) complexes of bidentate N‐heterocyclic carbene (NHC)/phosphane ligand L were
prepared and structurally characterized. Unlike palladium, which forms [PdCl2 (L)], the …

When phosphorus and NHC (N-heterocyclic carbene) meet each other

S Gaillard, JL Renaud - Dalton Transactions, 2013 - pubs.rsc.org
Since the discovery of the first air stable NHC, this class of compounds has been intensively
studied and applied in organometallic chemistry and homogeneous catalysis due to the …

Palladium Complexes of Planar Chiral Ferrocenyl Phosphine-NHC Ligands: New Catalysts for the Asymmetric Suzuki− Miyaura Reaction

N Debono, A Labande, E Manoury, JC Daran… - …, 2010 - ACS Publications
Air-stable neutral and cationic palladium complexes bearing chiral phosphine-N-
heterocyclic carbene ligands with planar chirality only have been prepared in moderate to …

Palladium complexes with ethylene-bridged bis (N-heterocyclic carbene) for C–C coupling reactions

HM Lee, CY Lu, CY Chen, WL Chen, HC Lin, PL Chiu… - Tetrahedron, 2004 - Elsevier
A series of new ethylene-bridged bis (imidazolium) halides with various N-substitutions were
synthesized. Complexation of these imidazolium halides with Pd (OAc) 2 produced new Pd …