Strong metal–support interaction in heterogeneous catalysts

Z Luo, G Zhao, H Pan, W Sun - Advanced Energy Materials, 2022 - Wiley Online Library
Strong metal–support interaction (SMSI) in supported metal catalysts, typically accompanied
by the formation of encapsulation layers over metal nanoparticles, has drawn intense …

Engineering heterogeneous catalysis with strong metal–support interactions: characterization, theory and manipulation

T Pu, W Zhang, M Zhu - Angewandte Chemie International …, 2023 - Wiley Online Library
Strong metal–support interactions (SMSI) represent a classic yet fast‐growing area in
catalysis research. The SMSI phenomenon results in the encapsulation and stabilization of …

Recent progress in heterogeneous metal and metal oxide catalysts for direct dehydrogenation of ethane and propane

Y Dai, X Gao, Q Wang, X Wan, C Zhou… - Chemical Society …, 2021 - pubs.rsc.org
Catalytic non-oxidative direct dehydrogenation of light alkanes serves as an effective
reinforcement to selectively produce the corresponding olefins, and the heterogeneous …

Metal–support interactions in metal oxide-supported atomic, cluster, and nanoparticle catalysis

D Leybo, UJ Etim, M Monai, SR Bare… - Chemical Society …, 2024 - pubs.rsc.org
Supported metal catalysts are essential to a plethora of processes in the chemical industry.
The overall performance of these catalysts depends strongly on the interaction of adsorbates …

Direct and oxidative dehydrogenation of propane: from catalyst design to industrial application

JH Carter, T Bere, JR Pitchers, DG Hewes… - Green …, 2021 - pubs.rsc.org
The direct formation of propene from propane is a well-established commercial process,
which on the basis of energy consumption, is environmentally preferred to the current large …

The dynamics of overlayer formation on catalyst nanoparticles and strong metal-support interaction

A Beck, X Huang, L Artiglia, M Zabilskiy, X Wang… - Nature …, 2020 - nature.com
Heterogeneous catalysts play a pivotal role in the chemical industry. The strong metal-
support interaction (SMSI), which affects the catalytic activity, is a phenomenon researched …

CO2 methanation over Ni nanoparticles inversely loaded with CeO2 and Cr2O3: Catalytic functions of metal oxide/Ni interfaces

J Tian, P Zheng, T Zhang, Z Han, W Xu, F Gu… - Applied Catalysis B …, 2023 - Elsevier
Interfaces between active metal and metal oxide in a heterogenous catalyst often play an
important role in catalysis. In this work, we intentionally synthesized a series of inverse CeO …

Renaissance of Strong Metal–Support Interactions

M Xu, M Peng, H Tang, W Zhou, B Qiao… - Journal of the American …, 2024 - ACS Publications
Strong metal–support interactions (SMSIs) have emerged as a significant and cutting-edge
area of research in heterogeneous catalysis. They play crucial roles in modifying the …

Illustrating new understanding of adsorbed water on silica for inducing tetrahedral cobalt (II) for propane dehydrogenation

Z Huang, D He, W Deng, G Jin, K Li, Y Luo - Nature Communications, 2023 - nature.com
Highly dispersed metal sites on the surface of silica, achieved from immobilization of metal
precursor within hydroxyl groups, has gained increasing attention in the field of …

Unraveling enhanced activity, selectivity, and coke resistance of Pt–Ni bimetallic clusters in dry reforming

J Niu, Y Wang, S E. Liland, S K. Regli, J Yang… - ACS …, 2021 - ACS Publications
By introducing Pt atoms into the surface of reduced hydrotalcite (HT)-derived nickel (Ni/HT)
catalysts by redox reaction, we synthesized an enhanced active and stable Ni-based …