Recent developments in azaborinine chemistry

G Bélanger‐Chabot, H Braunschweig… - European Journal of …, 2017 - Wiley Online Library
Recent years have witnessed rapid advances in the field of BN/CC isosterism, particularly in
the case of azaborinines. Examples of each isomer have now been synthesized and …

BN-embedded aromatics for optoelectronic applications

JY Wang, J Pei - Chinese Chemical Letters, 2016 - Elsevier
The knowledge of azaborine chemistry is growing as an important branch in organic
semiconductor materials. Specifically, BN-embedded aromatic compounds have attracted …

BN heterosuperbenzenes: synthesis and properties

XY Wang, JY Wang, J Pei - Chemistry–A European Journal, 2015 - Wiley Online Library
Abstract Replacement of C C unit with its isoelectronic B N unit in aromatics provides a
new class of molecules with appealing properties, which have attracted great attention …

Site-Selective and Stereoselective trans-Hydroboration of 1,3-Enynes Catalyzed by 1,4-Azaborine-Based Phosphine–Pd Complex

S Xu, Y Zhang, B Li, SY Liu - Journal of the American Chemical …, 2016 - ACS Publications
A concise synthesis of monobenzofused 1, 4-azaborine phosphine ligands (Senphos) is
described. These Senphos ligands uniquely support Pd-catalyzed trans-selective …

Synthesis, characterization and investigation of anticorrosion properties of an innovative metal–organic framework, ZnMOF-BTA, on carbon steel in HCl solution

IK Nwokolo, H Shi, AI Ikeuba, N Gao, J Li, S Ahmed… - Coatings, 2022 - mdpi.com
An innovative metal–organic framework (ZnMOF-BTA) with corrosion inhibition properties
was prepared by the solvothermal reaction of zinc nitrate, 1, 2, 3-benzotriazole, and 2, 5 …

Construction of Boron-Containing Aromatic Heterocycles

B Su, R Kinjo - Synthesis, 2017 - thieme-connect.com
Boron-containing aromatic systems exhibit unique electronic properties and reactivities that
have been extensively studied for a long time. This review highlights the recent …

Ring expansion reactions of anti-aromatic boroles: a promising synthetic avenue to unsaturated boracycles

JH Barnard, S Yruegas, K Huang… - Chemical …, 2016 - pubs.rsc.org
Conjugated boron heterocycles have emerged as attractive synthetic targets due to their
potential in medicinal chemistry and as electronic materials. However, the development of …

B2N2-Dibenzo[a,e]pentalenes: Effect of the BN Orientation Pattern on Antiaromaticity and Optoelectronic Properties

XY Wang, A Narita, X Feng… - Journal of the American …, 2015 - ACS Publications
Two BN units were embedded in dibenzo [a, e] pentalene with different orientation patterns,
which significantly modulated its antiaromaticity and optoelectronic properties. Importantly …

Rapid and Modular Access to Multifunctionalized 1, 2-Azaborines via Palladium/Norbornene Cooperative Catalysis

S Choi, G Dong - Journal of the American Chemical Society, 2024 - ACS Publications
1, 2-Azaborines, a unique class of BN-isosteres of benzene, have attracted great interest
across several fields. While significant advancements have been made in the …

Synthesis by free radical polymerization and properties of BN-polystyrene and BN-poly (vinylbiphenyl)

WM Wan, AW Baggett, F Cheng, H Lin… - Chemical …, 2016 - pubs.rsc.org
Free radical polymerization of B-vinyl-and B-styryl-functionalized azaborinine monomers
gives well-defined hybrid polymers that were fully characterized by multinuclear NMR and …