Metal organic complexation in seawater: Historical background and future directions

JW Moffett, RM Boiteau - Annual Review of Marine Science, 2024 - annualreviews.org
The speciation of most biologically active trace metals in seawater is dominated by
complexation by organic ligands. This review traces the history of work in this area, from the …

Marine microeukaryote metatranscriptomics: sample processing and bioinformatic workflow recommendations for ecological applications

NR Cohen, H Alexander, AI Krinos, SK Hu… - Frontiers in Marine …, 2022 - frontiersin.org
Microeukaryotes (protists) serve fundamental roles in the marine environment as
contributors to biogeochemical nutrient cycling and ecosystem function. Their activities can …

[HTML][HTML] Ligand exchange provides new insight into the role of humic substances in the marine iron cycle

CF Sukekava, J Downes, M Filella, B Vilanova… - … et Cosmochimica Acta, 2024 - Elsevier
Organic complexation of iron plays a crucial role in preventing its precipitation, facilitating its
transport, and modulating its reactivity and bioavailability in natural waters. Although humic …

Global niche partitioning of purine and pyrimidine cross-feeding among ocean microbes

R Braakman, B Satinsky, TJ O'Keefe, K Longnecker… - Science …, 2025 - science.org
Cross-feeding involves microbes consuming exudates of other surrounding microbes,
mediating elemental cycling. Characterizing the diversity of cross-feeding pathways in …

Metabolite diversity among representatives of divergent Prochlorococcus ecotypes

EB Kujawinski, R Braakman, K Longnecker… - Msystems, 2023 - Am Soc Microbiol
The euphotic zone of the surface ocean contains distinct physical-chemical regimes that
vary in light and nutrient concentrations as an inverse function of depth. The most numerous …

Toxic effects of nanoplastics on biological nitrogen removal in constructed wetlands: Evidence from iron utilization and metabolism

X Zhao, M Guo, Y Wang, M Jin, N Hou, H Wu - Water Research, 2024 - Elsevier
Nanoplastics (NPs) in wastewaters may present a potential threat to biological nitrogen
removal in constructed wetlands (CWs). Iron ions are pivotal in microbially mediated …

Photodegradation kinetics and deep learning-based intelligent colorimetric method for bioavailability-based dissolved iron speciation

J Luo, Z Huang, S Li, F Zheng, F Liu, Q Huang… - Analytical …, 2022 - ACS Publications
Via the photodegradation of dissolved iron (dFe) complexes in the euphotic zone, released
free Fe (III) is the most important source of bioavailable iron for eukaryotic phytoplankton …

Seasonal shifts in Fe‐acquisition strategies in Southern Ocean microbial communities revealed by metagenomics and autonomous sampling

R Zhang, P Debeljak, S Blain… - Environmental …, 2023 - Wiley Online Library
Iron (Fe) governs the cycling of organic carbon in large parts of the Southern Ocean. The
strategies of diverse microbes to acquire the different chemical forms of Fe under seasonally …

New insights into the organic complexation of bioactive trace metals in the global ocean from the GEOTRACES era

H Whitby, J Park, Y Shaked, RM Boiteau, KN Buck… - Oceanography, 2024 - JSTOR
The GEOTRACES program has greatly expanded measurements of dissolved trace metal
concentrations across ocean basins, but to understand the behavior and cycling of metals …

Contribution of cryoconite holes in the supraglacial discharge of bioavailable iron in Larsemann Hills, East Antarctica

G Samui, A Sanyal, R Antony, CM Laluraj, M Thamban - Polar Science, 2024 - Elsevier
Supraglacial discharge of limiting micronutrients such as iron (Fe) into high-nutrient low-
chlorophyll (HNLC) regions like the Southern Ocean has recently drawn global attention. In …