This review serves to document advances in the synthesis, versatile bonding, and reactivity
of molecular main group metal hydrides within Groups 1, 2, and 12–16. Particular attention …

Since the discovery that the so‐called “double‐bond” rule could be broken, the field of
molecular main group multiple bonds has expanded rapidly. With the majority of …

The construction of C (sp3)–Si bonds is important in synthetic, medicinal, and materials
chemistry. In this context, reactions mediated by silyl radicals have become increasingly …

The development of general and selective methods to generate and transform reactive
intermediates such as radicals, cations, and anions remains an important objective in …

Free phosphaborenes (R–P═ B–R) are PB analogues of alkynes, and their isolation is a
long-sought-after goal. Herein, we demonstrate that the combination of a π-donating and a π …

This review article summarizes recent progress in the synthesis and optoelectronic
properties of conjugated materials containing heavy main group elements from Group 13 …

In recent decades, cyclotriphosphazene (CTP) and its derivatives have garnered significant
attention due to their exceptional physical and chemical properties, such as remarkable …

The relationship between the monomer structure and polymer properties is central to
materials science. Here we discuss the notion of monomer dimensionality, as it refers to the …

Abstract The first 1, 4‐distibabenzene‐1, 4‐diide compound [(ADC) Sb] 2 (5) based on an
anionic dicarbene (ADC)(ADC= PhC {N (Dipp) C} 2, Dipp= 2, 6‐iPr2C6H3) is reported as a …

While the implication of the aromaticity concept has been dramatically expanded to date
since its emergence in 1865, the classical [4n+ 2]/4n-electron counting protocol still plays an …