Applying the ligand electrochemical parameter approach to sandwich complexes and standardizing to the FeIII/FeII couple, we obtained EL (L) values for over 200 π-ligands …
Electrochemical studies with transition metal sandwich complexes began to develop soon after the synthesis of ferrocene in 1951 [l]. Since then, a large number of sandwich …
S Ketkov - Dalton Transactions, 2020 - pubs.rsc.org
Recent advances on substituent effects in transition metal bisarene complexes studied with high-resolution threshold ionization spectroscopy are reviewed to demonstrate new aspects …
Chemical reduction of 2, 4, 6-tricyano-1, 3, 5-triazine, TCT, results in the formation of an unstable radical anion that undergoes immediate dimerization at a ring carbon to form …
SY Ketkov - Mendeleev Communications, 2024 - Elsevier
Laser photoionization spectroscopy provides extremely high accuracy in determining ionization energies of jet-cooled bisarene complexes, metallocenes and mixed sandwich …
SY Ketkov, GV Markin, SY Tzeng… - Chemistry–A European …, 2016 - Wiley Online Library
Mass‐analyzed threshold ionization spectra of jet‐cooled [(η6‐PhMe)(η6‐PhH) Cr] and [(η6‐ Ph2)(η6‐PhH) Cr] reveal with unprecedented accuracy the effects of methyl and phenyl …
SY Ketkov, SY Tzeng, PY Wu… - … –A European Journal, 2017 - Wiley Online Library
High‐resolution mass‐analyzed threshold ionization (MATI) spectra of (η6‐Ph2) 2Cr and (η6‐ Ph2)(η6‐PhMe) Cr demonstrate that the Ph groups work as electron donors, decreasing the …
WE Geiger - J. Organomet. Chem. Libr, 1990 - degruyter.com
The redox properties of transition metal sandwich complexes have been probed often since the discovery of the ferrocene/ferrocenium couple (Fc/Fc+) in an early paper [1]. Reviews in …
B Bildstein, O Loza, Y Chizhov - Organometallics, 2004 - ACS Publications
Density functional theory calculations for neutral and oxidized diferrocenyldiphenylcumulenes,[Fc (Ph) C n (Ph) Fc] with n= 2, 4, 6, 8, were performed at the …