Dynamic molecular crystals with switchable physical properties

O Sato - Nature chemistry, 2016 - nature.com
The development of molecular materials whose physical properties can be controlled by
external stimuli—such as light, electric field, temperature, and pressure—has recently …

Molecular spin crossover phenomenon: recent achievements and prospects

A Bousseksou, G Molnár, L Salmon… - Chemical Society …, 2011 - pubs.rsc.org
Recently we assisted a strong renewed interest in the fascinating field of molecular spin
crossover complexes by (1) the emergence of nanosized spin crossover materials through …

Switching the magnetic hysteresis of an [Feii–NC–Wv]-based coordination polymer by photoinduced reversible spin crossover

L Zhao, YS Meng, Q Liu, O Sato, Q Shi, H Oshio… - Nature Chemistry, 2021 - nature.com
Magnetic bistable materials that feature magnetic hysteresis are comparable to elementary
binary units and promising for application in switches and memory devices. In this work, we …

Light-induced spin-crossover magnet

S Ohkoshi, K Imoto, Y Tsunobuchi, S Takano… - Nature …, 2011 - nature.com
The light-induced phase transition between the low-spin (LS) and high-spin (HS) states of
some transition-metal ions has been extensively studied in the fields of chemistry and …

Challenges for developing photo-induced phase transition (PIPT) systems: from classical (incoherent) to quantum (coherent) control of PIPT dynamics

S Koshihara, T Ishikawa, Y Okimoto, K Onda, R Fukaya… - Physics Reports, 2022 - Elsevier
This work reviews the experimental studies on photo-induced cooperative phenomena
(photo-induced phase transitions, PIPT), which are related to ultrafast structural and …

Organic and molecular magnets

SJ Blundell, FL Pratt - Journal of Physics: Condensed Matter, 2004 - iopscience.iop.org
Historically most materials in magnetic applications are based on inorganic materials.
Recently, however, organic and molecular materials have begun to show increasing …

Optically switchable molecular solids: photoinduced spin-crossover, photochromism, and photoinduced magnetization

O Sato - Accounts of chemical research, 2003 - ACS Publications
A possible route to finding new optically switchable molecular solids is to investigate the
photoeffects of compounds that exhibit an abrupt phase transition or hysteresis loop. Such …

[HTML][HTML] Structural analysis of spin-crossover materials: From molecules to materials

E Collet, P Guionneau - Comptes Rendus Chimie, 2018 - Elsevier
In molecular spin-crossover materials, the spin-state switching is strongly coupled with
changes in the structural degrees of freedom, which play a central role in the alteration of …

The spin-states and spin-transitions of mononuclear iron (II) complexes of nitrogen-donor ligands

MA Halcrow - Polyhedron, 2007 - Elsevier
A survey of mononuclear iron (II) complexes with heterocyclic N-donor ligation is presented.
A brief introduction to spin-crossover chemistry and low-temperature spin-trapping is …

A light-induced spin crossover actuated single-chain magnet

T Liu, H Zheng, S Kang, Y Shiota, S Hayami… - Nature …, 2013 - nature.com
Both spin-crossover complexes and molecular nanomagnets display bistable magnetic
states, potentially behaving as elementary binary units for information storage. It is a …