[AuI(CN)2]-Armed [FeIII2FeII2] Square Complex Showing Unusual Spin-Crossover Behavior Due to a Symmetry-Breaking Phase Transition

M You, D Shao, YF Deng, J Yang, NT Yao… - Inorganic …, 2022 - ACS Publications
The incorporation of two different cyanide building blocks of [(TpR) FeIII (CN) 3]− and [AuI
(CN) 2]− into one molecule afforded a novel hexanuclear [FeIII2FeII2AuI2] complex (1· 2Et 2 …

Construction of spin-crossover dinuclear cobalt (II) compounds based on complementary terpyridine ligand pairing

SY Zhang, HY Sun, RG Wang, YS Meng, T Liu… - Dalton …, 2022 - pubs.rsc.org
The self-assembly of multinuclear SCO complexes is appealing in which unique properties
may be discovered due to enhanced intramolecular and intermolecular interactions. In this …

Cyanide-Bridged Fe-Co Polynuclear Clusters Based on Four-Coordinate Cobalt (II)

Y Cheng, ZY Chen, KP Xie, YF Deng, YX Jiang… - Inorganic …, 2020 - ACS Publications
Treatment of CoCl2· 6H2O and tris (pyrazolyl-1-yl) borate tricyanoiron (III) anions at 55° C
afforded a series of new Fe-Co polynuclear clusters:{Co2Cl2 (DMF) 4 [(Tp4-Me) Fe (CN) 3] …

[HTML][HTML] Manipulation of the cyanido-bridged Fe2W2 rhombus in the crystalline state: Co-crystallization, desolvation and thermal treatment

J Kobylarczyk, P Pakulski, I Potępa, R Podgajny - Polyhedron, 2022 - Elsevier
We present the new cyanido-bridged rhombus {[Fe II (TPMA)] 2 [WV (CN) 8] 2} 2–(Fe 2 W
2)(TPMA= tris (2-pyridylmethyl) amine) cluster as a potential Secondary Building Block …

Synthesis and structural characterization of a silver (I) pyrazolato coordination polymer

K Fujisawa, T Nemoto, Y Morishima, DB Leznoff - Molecules, 2021 - mdpi.com
Coinage metal (I)··· metal (I) interactions are widely of interest in fields such as
supramolecular assembly and unique luminescent properties, etc. Only two types of …

SPIN CROSSOVER IN IRON(II) COMPLEXES WITH TRIS(PYRAZOL-1-YL)METHANE AND [Ag(CN)2] AND [Au(CN)2] ANIONS

OG Shakirova, EV Korotaev, SA Petrov… - Journal of Structural …, 2022 - Springer
New coordination compounds of iron (II) with tris (pyrazol-1-yl) methane (HC (pz) 3)
containing dicyanoargentate and dicyanoaurate ions of the composition [Fe (HC (pz) 3)[Ag …

Unusual reactions of potassium dihalodicyanoaurates with organyltriphenylphosphonium halides

DP Shevchenko, VV Sharutin - Russian Journal of Coordination Chemistry, 2023 - Springer
Precipitates synthesized by the reactions of potassium dichloro-and dibromodicyanoaurates
with tetraphenylphosphonium, cyanomethyltriphenylphosphonium, and …

Pyridyl-Thioethers as Capping Ligands for the Design of Heteroleptic Fe (II) Complexes with Spin-Crossover Behavior

Ö Üngör, D Igimbayeva, A Dragulescu-Andrasi… - Magnetochemistry, 2021 - mdpi.com
Mononuclear heteroleptic complexes [Fe (tpma)(bimz)](ClO4) 2 (1a),[Fe (tpma)(bimz)](BF4)
2 (1b),[Fe (bpte)(bimz)](ClO4) 2 (2a), and [Fe (bpte)(bimz)](BF4) 2 (2b)(tpma= tris (2 …

Synthesis Methods, Structure, and Applications of Metal Dicyanoaurate, Tetracyanoaurate, and Dihalodicyanoaurate Complexes

DP Shevchenko - Reviews and Advances in Chemistry, 2023 - Springer
Cyanoaurate complexes represent a broad class of compounds with diverse structures. In
particular, coordination polymers based on these complexes have numerous potential …

[HTML][HTML] МЕТОДЫ СИНТЕЗА, СТРОЕНИЕ И ПРИМЕНЕНИЕ ДИ-, ТЕТРАИ ДИГАЛОГЕНДИЦИАНОАУРАТОВ МЕТАЛЛОВ

ДП Шевченко - Вестник Южно-Уральского государственного …, 2023 - cyberleninka.ru
Цианоауратные комплексы представляют собой широкий класс соединений с
разнообразной структурой. В частности, координационные полимеры на их основе …