Coordination complexes of bismuth (III) involving organic ligands with pnictogen or chalcogen donors

GG Briand, N Burford - 2000 - Elsevier
Publisher Summary The chapter presents an overview of the structural diversity
demonstrated by complexes of bismuth (III) with organic-based ligands involving the …

Self-Assembly of Complementary Components Using a Tripodal Bismuth Compound: Pnictogen Bonding or Coordination Chemistry?

S Moaven, BT Watson, TJ Polaske, BM Karl… - Inorganic …, 2021 - ACS Publications
Triple pnictogen bonding refers to the ability of a pnictogen atom to engage in three
simultaneous pnictogen bonds (PnBs) to a complementary partner through a single …

Expanding Bismuth Trihalide Coordination Chemistry with Trimethyltriazacyclohexane and Trimethyltriazacyclononane

JC Wedal, JW Ziller, WJ Evans - Inorganic Chemistry, 2022 - ACS Publications
1, 3, 5-Trimethyltriazacyclohexane, Me3tach, readily adds to bismuth triiodide to form a
variety of new coordination compounds depending on the stoichiometry, solvent, and …

Синтез, строение и применение арильных соединений висмута

ВВ Шарутин, ТВ Мосунова - Вестник Южно-Уральского …, 2020 - cyberleninka.ru
На основе анализа литературы, опубликованной за период с конца XX века до начала
XXI века, систематизированы и описаны методы получения, некоторые реакции …

Supramolecular assemblies of germanium (ii) halides with O-, S-and Se-donor macrocycles–the effects of donor atom type upon structure

AL Hector, W Levason, G Reid, M Webster… - Dalton …, 2011 - pubs.rsc.org
Reaction of [GeCl2 (dioxane)] with [18] aneS6 (1, 4, 7, 10, 13, 16-hexathiacyclooctadecane)
gives the neutral [GeCl2 ([18] aneS6)] which forms a supramolecular sheet network …

Bismuth (III) coordination compounds. Synthesis, characterization, and X-ray structures of [Bi (Cl)(μ-Cl) 2 (THF) 2]∞, Bi (O2CMe) 3 (Solv) x (Solv= py, x= 2 or MeIm, x …

TJ Boyle, DM Pedrotty, B Scott, JW Zillere - Polyhedron, 1998 - Elsevier
We have isolated and structurally characterized several novel bismuth coordination
compounds. Dissolution of Bi (NO3) 3· 5H2O in concentrated HCl, followed by crystallization …

Azamacrocyclic stabilisation of the halogenocations MX 3+ where M= Ge or Sn and X= Cl or Br. Synthesis and molecular structures of [GeCl 3 (L 1)]+ 2 [H 3 O]+ Cl–3 …

GR Willey, TJ Woodman, U Somasundaram… - Journal of the …, 1998 - pubs.rsc.org
Treatment (1∶ 1 in acetonitrile) of the reaction systems MCl4–1, 4, 7-trimethyl-1, 4, 7-
triazacyclononane (L1) and MBr4–1, 3, 5-trimethyl-1, 3, 5-triazacyclohexane (L2), where …

Adducts of indium (III) bromide: synthesis and structural characterisation of [InBr3 (THF) 2],[InBr3 (DMF) 3],[InBr3 (Me3 [9] aneN3)] and [InBr3 ({–N (Me)–CH2–} 3)]

GR Willey, DR Aris, JV Haslop, W Errington - Polyhedron, 2001 - Elsevier
Treatment of InBr3 with THF gives InBr3 (THF) 2. A crystal structure determination (X-ray
diffraction) reveals that the five co-ordinate metal centre adopts a trigonal bipyramidal …

Controlled hydrolysis reactions of the Group 15 element–azamacrocyclic complexes MCl 3 L (M= As, Sb or Bi; L= 1, 4, 7-trimethyl-1, 4, 7-triazacyclononane) …

GB Michael - Journal of the Chemical Society, Dalton Transactions, 1996 - pubs.rsc.org
Reactions of MCl3 (M= As, Sb or Bi) and 1, 4, 7-trimethyl-1, 4, 7-triazacyclononane (Me3 [9]
aneN3= L) gave the respective 1: 1 adducts as white-yellow microcrystalline solids which …

Azamacrocyclic stabilization of SbCl2+: synthesis and crystal structure of [SbCl2 (Me3 [9] aneN3)][SbCl6] showing explicit SbIII lone-pair stereochemical activity. Me3 …

GR Willey, MP Spry, MGB Drew - Polyhedron, 1996 - Elsevier
The reaction of antimony (III) chloride and antimony (V) chloride in acetonitrile in the
presence of the azamacrocyclic ligand Me3 [9] aneN3 provides the golden-yellow ionic …