Polymers without petrochemicals: sustainable routes to conventional monomers

G Hayes, M Laurel, D MacKinnon, T Zhao… - Chemical …, 2022 - ACS Publications
Access to a wide range of plastic materials has been rationalized by the increased demand
from growing populations and the development of high-throughput production systems …

Homogeneous catalysis for sustainable hydrogen storage in formic acid and alcohols

K Sordakis, C Tang, LK Vogt, H Junge… - Chemical …, 2018 - ACS Publications
Hydrogen gas is a storable form of chemical energy that could complement intermittent
renewable energy conversion. One of the main disadvantages of hydrogen gas arises from …

Homogeneous transition metal catalysis of acceptorless dehydrogenative alcohol oxidation: applications in hydrogen storage and to heterocycle synthesis

RH Crabtree - Chemical Reviews, 2017 - ACS Publications
The different types of acceptorless alcohol dehydrogenation (AAD) reactions are discussed,
followed by the catalysts and mechanisms involved. Special emphasis is put on the common …

Bond activation and catalysis by ruthenium pincer complexes

C Gunanathan, D Milstein - Chemical reviews, 2014 - ACS Publications
Activation of inert chemical bonds by transition metal complexes is an area of utmost
importance. Efficient bond activation can provide a leading entry to successful catalytic …

Low-temperature aqueous-phase methanol dehydrogenation to hydrogen and carbon dioxide

M Nielsen, E Alberico, W Baumann, HJ Drexler… - Nature, 2013 - nature.com
Hydrogen produced from renewable resources is a promising potential source of clean
energy. With the help of low-temperature proton-exchange membrane fuel cells, molecular …

Dehydrogenation as a substrate-activating strategy in homogeneous transition-metal catalysis

GE Dobereiner, RH Crabtree - Chemical reviews, 2010 - ACS Publications
The rise of green chemistry has drawn attention to bond construction strategies that promote
atom economy and avoid mutagenic reagents. 1 For example, both goals are achieved by …

Recent advances in liquid organic hydrogen carriers: an alcohol-based hydrogen economy

V Yadav, G Sivakumar, V Gupta, E Balaraman - ACS Catalysis, 2021 - ACS Publications
Energy storage and the use of abundantly available feedstock without contributing to the
carbon footprint are two significant global challenges. In this regard, the development of high …

Catalytic oxidation of organic substrates by molecular oxygen and hydrogen peroxide by multistep electron transfer—a biomimetic approach

J Piera, JE Bäckvall - Angewandte Chemie International …, 2008 - Wiley Online Library
Oxidation reactions are of fundamental importance in nature, and are key transformations in
organic synthesis. The development of new processes that employ transition metals as …

[PDF][PDF] Ruthenium-catalyzed reactions for organic synthesis

T Naota, H Takaya, SI Murahashi - Chemical reviews, 1998 - academia.edu
Metal-catalyzed reactions have made a great contribution to the recent growth of organic
synthesis, and a variety of synthetic methods have been reported using mainly group 8 …

Dehydrogenative oxidation of alcohols in aqueous media using water-soluble and reusable Cp* Ir catalysts bearing a functional bipyridine ligand

R Kawahara, K Fujita, R Yamaguchi - Journal of the American …, 2012 - ACS Publications
A new catalytic system for the dehydrogenative oxidation of alcohols using a water-soluble
Cp* Ir complex bearing a bipyridine-based functional ligand as catalyst has been …