Excited-state symmetry breaking is an ultrasensitive tool for probing microscopic electric fields
Microscopic electric fields are increasingly found to play a pivotal role in catalysis of
enzymatic and chemical reactions. Currently, the vibrational Stark effect is the main …
enzymatic and chemical reactions. Currently, the vibrational Stark effect is the main …
The effect of rigidity on the emission of quadrupolar strongly polarized dyes
Hybrid dyes comprising 1, 4-dihydropyrrolo [3, 2-b] pyrrole and two strongly electron-
withdrawing benzoxadiazole substituents, differing in their level of planarization, offer an …
withdrawing benzoxadiazole substituents, differing in their level of planarization, offer an …
Shedding new light on quadrupolar 1, 4-dihydropyrrolo [3, 2-b] pyrroles: impact of electron-deficient scaffolds over emission
In this work, we disclose a series of seven quadrupolar centrosymmetric 1, 4-dihydropyrrolo
[3, 2-b] pyrroles (DHPPs) linked to the two peripheral, strongly electron-accepting …
[3, 2-b] pyrroles (DHPPs) linked to the two peripheral, strongly electron-accepting …
1,4-Dihydropyrrolo[3,2-b]pyrroles with Two Embedded Heptagons via Alkyne Annulation
G Sanil, Ł Dobrzycki, MK Cyrański… - The Journal of …, 2025 - ACS Publications
Drastic changes to the character of the acidic catalyst enable the reversal of the double
alkyne benzannulation reaction output. In the presence of a strong Brønsted acid, 1, 4 …
alkyne benzannulation reaction output. In the presence of a strong Brønsted acid, 1, 4 …
Strongly Polarized π-Extended 1,4-Dihydropyrrolo[3,2-b]pyrroles Fused with Tetrazolo[1,5-a]quinolines
MB Teimouri, I Deperasinska, M Rammo… - The Journal of …, 2024 - ACS Publications
A straightforward route to 1, 4-dihydropyrrolo [3, 2-b] pyrroles comprised of two electron-
withdrawing quinoline or tetrazolo [1, 5-a] quinoline scaffolds has been developed. The …
withdrawing quinoline or tetrazolo [1, 5-a] quinoline scaffolds has been developed. The …
Poly (dimethylsiloxane) as a room-temperature solid solvent for photophysics and photochemistry
Medium viscosity strongly affects the dynamics of solvated species and can drastically alter
the deactivation pathways of their excited states. This study demonstrates the utility of poly …
the deactivation pathways of their excited states. This study demonstrates the utility of poly …