Nanoconfined ionic liquids

S Zhang, J Zhang, Y Zhang, Y Deng - Chemical Reviews, 2017 - ACS Publications
Ionic liquids (ILs) have been widely investigated as novel solvents, electrolytes, and soft
functional materials. Nevertheless, the widespread applications of ILs in most cases have …

Immobilized functional ionic liquids: efficient, green, and reusable catalysts

H Li, PS Bhadury, B Song, S Yang - RSC advances, 2012 - pubs.rsc.org
Ionic liquids (ILs) which are made up of cationic and anionic components can be designed
to possess a definite set of properties. In this context, the term “designer solvents” has been …

Featuring Xantphos

PWNM van Leeuwen, PCJ Kamer - Catalysis Science & Technology, 2018 - pubs.rsc.org
This review highlights the use of a bisphosphine ligand group in homogeneous catalysis.
This ligand group is known as the Xantphos-like ligands, which are based on the generic …

Fifteen years of supported ionic liquid phase-catalyzed hydroformylation: material and process developments

JM Marinkovic, A Riisager, R Franke… - Industrial & …, 2018 - ACS Publications
This review describes the development of supported ionic liquid phase (SILP) materials as
novel hydroformylation catalysts. Ligand-modified rhodium catalysts can be immobilized in a …

Ionic Liquids in Metal, Photo-, Electro-, and (Bio) Catalysis

J Dupont, BC Leal, P Lozano, AL Monteiro… - Chemical …, 2024 - ACS Publications
Ionic liquids (ILs) have unique physicochemical properties that make them advantageous for
catalysis, such as low vapor pressure, non-flammability, high thermal and chemical …

Single atom dispersed Rh-biphephos&PPh 3@ porous organic copolymers: highly efficient catalysts for continuous fixed-bed hydroformylation of propene

C Li, L Yan, L Lu, K Xiong, W Wang, M Jiang, J Liu… - Green …, 2016 - pubs.rsc.org
A vinyl functionalized biphephos ligand with high steric hindrance was copolymerized with
tris (4-vinphenyl) phosphane and other ligands to afford efficient porous organic copolymers …

Current state of the art of the solid Rh-based catalyzed hydroformylation of short-chain olefins

S Hanf, L Alvarado Rupflin, R Gläser, SA Schunk - Catalysts, 2020 - mdpi.com
The hydroformylation of olefins is one of the most important homogeneously catalyzed
processes in industry to produce bulk chemicals. Despite the high catalytic activities and …

Small molecules, non-covalent interactions, and confinement

G Buntkowsky, M Vogel - Molecules, 2020 - mdpi.com
This review gives an overview of current trends in the investigation of small guest molecules,
confined in neat and functionalized mesoporous silica materials by a combination of solid …

Experimental and computational studies of carbon–Carbon bond formation via ketonization and aldol condensation over site-isolated zirconium catalysts

S Shylesh, LA Bettinson, A Aljahri… - ACS …, 2020 - ACS Publications
We report here the preparation and investigation of isolated Zr centers supported on a high
surface area silica for the conversion of carboxylic acids to internal ketones by ketonic …

A fully integrated continuous‐flow system for asymmetric catalysis: Enantioselective hydrogenation with supported ionic liquid phase catalysts using supercritical CO2 …

U Hintermair, G Franciò… - Chemistry–A European …, 2013 - Wiley Online Library
A continuous‐flow process based on a chiral transition‐metal complex in a supported ionic
liquid phase (SILP) with supercritical carbon dioxide (scCO2) as the mobile phase is …