A twist on the reaction of the CN radical with methylamine in the interstellar medium: new hints from a state-of-the-art quantum-chemical study

C Puzzarini, Z Salta, N Tasinato, J Lupi… - Monthly Notices of …, 2020 - academic.oup.com
Despite the fact that the majority of current models assume that interstellar complex organic
molecules (iCOMs) are formed on dust–grain surfaces, there is some evidence that neutral …

Exploring the Chemical Dynamics of Phenylethynyl Radical (C6H5CC; X2A1) Reactions with Allene (H2CCCH2; X1A1) and Methylacetylene (CH3CCH; X1A1)

SJ Goettl, Z Yang, S Kollotzek, D Paul… - The Journal of …, 2023 - ACS Publications
The bimolecular gas-phase reactions of the phenylethynyl radical (C6H5CC, X2A1) with
allene (H2CCCH2), allene-d 4 (D2CCCD2), and methylacetylene (CH3CCH) were studied …

One Collision—Two Substituents: Gas‐Phase Preparation of Xylenes under Single‐Collision Conditions

IA Medvedkov, AA Nikolayev, C He… - Angewandte Chemie …, 2024 - Wiley Online Library
The fundamental reaction pathways to the simplest dialkylsubstituted aromatics—xylenes
(C6H4 (CH3) 2)—in high‐temperature combustion flames and in low‐temperature …

A combined experimental and computational study on the reaction dynamics of the 1-propynyl (CH3CC, X2A1)–propylene (CH3CHCH2, X1A′) system: formation of …

IA Medvedkov, AA Nikolayev, C He, Z Yang… - Molecular …, 2024 - Taylor & Francis
The reaction of the 1-propynyl radical (CH3CC; X2A1) with propylene (CH3CHCH2; X1A′)
was studied in a crossed molecular beam machine at a collision energy of 37±1 kJ mol− 1 …

Elucidating the chemical dynamics of the elementary reactions of the 1-propynyl radical (CH 3 CC; X 2 A 1) with 2-methylpropene ((CH 3) 2 CCH 2; X 1 A 1)

IA Medvedkov, AA Nikolayev, Z Yang… - Physical Chemistry …, 2024 - pubs.rsc.org
Exploiting the crossed molecular beam technique, we studied the reaction of the 1-propynyl
radical (CH3CC; X2A1) with 2-methylpropene (isobutylene;(CH3) 2CCH2; X1A1) at a …

Exploring the chemical dynamics of phenanthrene (C 14 H 10) formation via the bimolecular gas-phase reaction of the phenylethynyl radical (C 6 H 5 CC) with …

SJ Goettl, Z Yang, C He, A Somani… - Faraday …, 2024 - pubs.rsc.org
The exploration of the fundamental formation mechanisms of polycyclic aromatic
hydrocarbons (PAHs) is crucial for the understanding of molecular mass growth processes …

Gas-Phase Formation of C5H6 Isomers via the Crossed Molecular Beam Reaction of the Methylidyne Radical (CH; X2Π) with 1,2-Butadiene (CH3CHCCH2; X1A …

C He, AA Nikolayev, L Zhao, AM Thomas… - The Journal of …, 2021 - ACS Publications
The bimolecular gas-phase reaction of the methylidyne radical (CH; X2Π) with 1, 2-
butadiene (CH2CCHCH3; X1A′) was investigated at a collision energy of 20.6 kJ mol–1 …