In industries and academic laboratories, several late transition metal-catalyzed prerequisite
reactions are widely performed during single and multistep synthesis. However, besides the …

Catalytic C–H bond activation, which was an elusive subject of chemical research until the
1990s, has now become a standard synthetic method for the formation of new C–C and C …

The present review “Iron Catalysis in Organic Synthesis” covers the literature until the end of
June 2014 and represents a comprehensive update of a previous article published by Bolm …

For more than 30 years, palladium has been extensively employed in the Suzuki–Miyaura
cross coupling reaction (SMCR) for the synthesis of C–C coupled products. However, Pd …

Sulfones are common, readily available reagents that have recently attracted attention as
versatile reagents for cross-coupling reactions. This Review summarizes advances in …

The palladium-catalyzed Mizoroki–Heck reaction is arguably one of the most significant
carbon–carbon bond-construction reactions to be discovered in the last 50 years, with a …

This review deals with some key synthetic developments based on the use of iron or cobalt
complexes to promote radical reactivity which have been devised over the last decades. We …

Cross-couplings of alkyl halides and organometallic species based on single electron
transfer using Ni and Fe catalyst systems have been studied extensively, and separately, for …

The scarcity of precious metals has led to the development of sustainable strategies for
metal‐catalyzed cross‐coupling reactions. The establishment of new catalytic methods …

Conspectus The catalytic cross-coupling reactions of organic halides or related substrates
with organometallic nucleophiles form the cornerstone of many carbon–carbon bond …