From macromonomers to bottlebrush copolymers with sequence control: synthesis, properties, and applications

KH Kim, J Nam, J Choi, M Seo, J Bang - Polymer Chemistry, 2022 - pubs.rsc.org
Bottlebrush polymers (BBPs) are a type of comb-like macromolecule with densely grafted
polymeric sidechains attached to the polymer backbones, and many intriguing properties …

Depolymerization of P(PDMS11MA) Bottlebrushes via Atom Transfer Radical Polymerization with Activator Regeneration

MR Martinez, S Dadashi-Silab, F Lorandi… - …, 2021 - ACS Publications
Depolymerization of vinyl polymers into monomers is energy-intensive due to the high
thermal and chemical stability of the backbone. Depolymerizations of methacrylic polymers …

Influence of the Norbornene Anchor Group in Ru-Mediated Ring-Opening Metathesis Polymerization: Synthesis of Bottlebrush Polymers

SJ Scannelli, M Alaboalirat, D Troya… - Macromolecules, 2023 - ACS Publications
Ring-opening metathesis polymerization (ROMP) mediated by Grubbs' third-generation
catalyst [G3,(H2IMes)(Cl) 2 (pyr) 2RuCHPh] is widely used to make bottlebrush polymers by …

Divergent synthesis of graft and branched copolymers through spatially controlled photopolymerization in flow reactors

N Corrigan, FJ Trujillo, J Xu, G Moad, CJ Hawker… - …, 2021 - ACS Publications
In this work, we demonstrate the controlled synthesis of graft and branched copolymers
using one-pot (batch) or one-pass (flow) processes without intermediate purification. The …

Self-healing bottlebrush polymer networks enabled via a side-chain interlocking design

H Xiong, T Yue, Q Wu, L Zhang, Z Xie, J Liu… - Materials …, 2023 - pubs.rsc.org
Exploring novel healing mechanisms is a constant impetus for the development of self-
healing materials. Herein, we find that side-chain interlocking of bottlebrush polymers can …

Independently tuning elastomer softness and firmness by incorporating side chain mixtures into bottlebrush network strands

AN Keith, C Clair, A Lallam, EA Bersenev… - …, 2020 - ACS Publications
Softness and firmness are opposing traits that synergistically define the elastic response of
biological systems. Currently, no single class of synthetic materials including elastomers and …

3D printable soft and solvent-free thermoplastic elastomer containing dangling bottlebrush chains

V Asadi, R Dolleman, J van der Gucht… - Materials Advances, 2023 - pubs.rsc.org
Polymer networks containing bottlebrush chains are emerging materials with exceptionally
soft and highly tunable mechanical properties. However, such materials have not been …

Searching for the synthetic methods towards siloxane molecular brushes

MA Obrezkova, AA Selifanova, VK Revenko… - Russian Chemical …, 2024 - Springer
The present review is devoted to the search for the possible methods to synthesize siloxane
molecular brushes (MBs). Wide diversity of chemical nature and architectures offered by …

Topologically designed cross-linking network for stretchable and recoverable pressure-sensitive adhesives with exceptional softness

MB Yi, TH Lee, SJ Lee, JS Kim, HJ Kim - Materials Today Chemistry, 2022 - Elsevier
There is an increasing demand for soft-electronic devices. Such devices require adhesives
that demonstrate appropriate stretching and recovery to support the assembly of various …

Safety-enhanced polymer electrolytes with high ambient-temperature lithium-ion conductivity based on ABA triblock copolymers

D Liu, F Wu, ZH Shen, XH Fan - Chinese Journal of Polymer Science, 2022 - Springer
Liquid electrolytes used in lithium-ion batteries suffer from leakage, flammability, and lithium
dendrites, making polymer electrolyte a potential alternative. Herein, a series of ABA triblock …