Artificial selenoenzymes: designed and redesigned
X Huang, X Liu, Q Luo, J Liu, J Shen - Chemical Society Reviews, 2011 - pubs.rsc.org
Enzymes, highly evolved machinery developed by nature, catalyse reactions with formidable
efficiency and specificity under mild conditions. Considerable efforts have been devoted for …
efficiency and specificity under mild conditions. Considerable efforts have been devoted for …
[HTML][HTML] Catalytic application of selenium and tellurium compounds as glutathione peroxidase enzyme mimetics
This review covers the past decade of intensive research on the design, synthesis and
screening of organoselenides and tellurides as catalyst able to mimic the activity of the …
screening of organoselenides and tellurides as catalyst able to mimic the activity of the …
Oxidative polymerization in living cells
Intracellular polymerization is an emerging technique that can potentially modulate cell
behavior, but remains challenging because of the complexity of the cellular environment …
behavior, but remains challenging because of the complexity of the cellular environment …
Diselenides and allyl selenides as glutathione peroxidase mimetics. Remarkable activity of cyclic seleninates produced in situ by the oxidation of allyl ω-hydroxyalkyl …
TG Back, Z Moussa - Journal of the American Chemical Society, 2003 - ACS Publications
A series of aliphatic diselenides and selenides containing coordinating substituents was
tested for glutathione peroxidase (GPx)-like catalytic activity in a model system in which the …
tested for glutathione peroxidase (GPx)-like catalytic activity in a model system in which the …
Intracellular hyperbranched polymerization for circumventing cancer drug resistance
Polymerization inside living cells provides chemists with a multitude of possibilities to
modulate cell activities. Considering the advantages of hyperbranched polymers, such as a …
modulate cell activities. Considering the advantages of hyperbranched polymers, such as a …
GPx-Like activity of selenides and selenoxides: Experimental evidence for the involvement of hydroxy perhydroxy selenane as the active species
The reaction mechanism of the GPx-like oxidation of PhSH with H2O2 catalyzed by
selenoxides proceeds via formation of the hydroxy perhydroxy selenane, which is a stronger …
selenoxides proceeds via formation of the hydroxy perhydroxy selenane, which is a stronger …
Tetravalent Spiroselenurane Catalysts: Intramolecular Se···N Chalcogen Bond-Driven Catalytic Disproportionation of H2O2 to H2O and O2 and Activation of I2 and …
Chalcogen-bonding interactions have recently gained considerable attention in the field of
synthetic chemistry, structure, and bonding. Here, three organo-spiroselenuranes, having a …
synthetic chemistry, structure, and bonding. Here, three organo-spiroselenuranes, having a …
o-Hydroxylmethylphenylchalcogens: Synthesis, Intramolecular Nonbonded Chalcogen···OH Interactions, and Glutathione Peroxidase-like Activity
The synthesis and characterization of a series of organochalcogen (Se, Te) compounds
derived from benzyl alcohol 13 are described. The synthesis of the key precursor …
derived from benzyl alcohol 13 are described. The synthesis of the key precursor …
Synthesis, properties, and photodynamic properties in vitro of heavy-chalcogen analogues of tetramethylrosamine
Thio and seleno analogues of tetramethylrosamine were prepared by the directed-
metalation/cyclization of the corresponding N, N-diethyl 2-(3 …
metalation/cyclization of the corresponding N, N-diethyl 2-(3 …
A convenient and efficient copper-catalyzed synthesis of unsymmetrical and symmetrical diaryl chalcogenides from arylboronic acids in ethanol at room temperature
A simple and convenient approach for the synthesis of unsymmetrical diaryl chalcogenides
(Te, Se, and S) has been developed by copper-catalyzed cross-coupling reaction of …
(Te, Se, and S) has been developed by copper-catalyzed cross-coupling reaction of …