Endohedral fullerenes

AA Popov, S Yang, L Dunsch - Chemical reviews, 2013 - ACS Publications
One of the attractive properties of the hollow carbon clusters, known as fullerenes, is the
possibility to use them as robust containers for other species. Although an IUPAC …

Chemical, electrochemical, and structural properties of endohedral metallofullerenes

MN Chaur, F Melin, AL Ortiz… - Angewandte Chemie …, 2009 - Wiley Online Library
Ever since the first experimental evidence of the existence of endohedral metallofullerenes
(EMFs) was obtained, the search for carbon cages with encapsulated metals and small …

Small-bandgap endohedral metallofullerenes in high yield and purity

S Stevenson, G Rice, T Glass, K Harich, F Cromer… - Nature, 1999 - nature.com
The idea that fullerenes might be able to encapsulate atoms and molecules has been
verified by the successful synthesis of a range of endohedral fullerenes, in which metallic or …

M2@C79N (M = Y, Tb): Isolation and Characterization of Stable Endohedral Metallofullerenes Exhibiting M−M Bonding Interactions inside Aza[80]fullerene Cages

T Zuo, L Xu, CM Beavers, MM Olmstead… - Journal of the …, 2008 - ACS Publications
Y2@ C79N and Tb2@ C79N have been prepared by conducting the Krätschmer− Huffman
electric-arc process under 20 Torr of N2 and 280 Torr of He with metal oxide-doped graphite …

Colossal C130 Fullertubes: Soluble [5,5] C130-D5h(1) Pristine Molecules with 70 Nanotube Carbons and Two 30-Atom Hemifullerene End-caps

E Bourret, X Liu, CA Noble, K Cover… - Journal of the …, 2023 - ACS Publications
We report the seminal experimental isolation and DFT characterization of pristine [5, 5] C130-
D5h (1) fullertubes. This achievement represents the largest soluble carbon molecule …

Fullertubes: A 30-Year Story of Prediction, Experimental Validation, and Applications for a Long-Missing Family of Soluble Carbon Molecules

S Stevenson, HC Dorn - Accounts of Chemical Research, 2024 - ACS Publications
Conspectus During the last 30 years, theoretical scientists imagined segmental families of
monolayer carbon tubules with fullerene-based end-caps. These fullertube molecules would …

A Large Family of Dysprosium-based Trimetallic Nitride Endohedral Fullerenes:  Dy3N@C2n (39 ≤ n ≤ 44)

S Yang, L Dunsch - The Journal of Physical Chemistry B, 2005 - ACS Publications
Dysprosium-based trimetallic nitride endohedral fullerenes (clusterfullerenes) the Dy3N@
C2 n (38≤ n≤ 49) family have been produced at overwhelming yields compared to the …

Polarizability as a landmark property for fullerene chemistry and materials science

DS Sabirov - Rsc Advances, 2014 - pubs.rsc.org
The review summarizes data on dipole polarizability of fullerenes and their derivatives,
covering the most widespread classes of fullerene-containing molecules (fullerenes …

Expanding the World of Endohedral Fullerenes—The Tm3N@C2n (39≤n≤43) Clusterfullerene Family

M Krause, J Wong, L Dunsch - Chemistry–A European Journal, 2005 - Wiley Online Library
A new family of endohedral fullerenes, based on an encaged trithulium nitride (Tm3N)
cluster, was synthesised, isolated and characterised by HPLC, mass spectrometry, and …

Recent progress in the studies of endohedral metallofullerenes

S Liu, S Sun - Journal of Organometallic Chemistry, 2000 - Elsevier
This overview presents the recent progress in the area of endohedral metallofullerenes in
the past several years. The important results have been summarized as follows:(1) Many …