Heavier alkene analogues possess unique electronic properties and reactivity, encouraging
multidisciplinary research groups to utilize them in the rational design of novel classes of …

We present an approach for preparing chain-type unsaturated molecules with low oxidation
state Si (I) and Sb (I) supported by amidinato ligands that exploit to generate heavy …

Herein we report the reduction of R‐EX2 (E= P, Sb) with two equivalents of KC8 in the
presence of silylene (LSiR; L= PhC (NtBu) 2) to give Trip‐P= SiL (C6H4PPh2)(1), TerPh …

Discovering new bonding scenarios and subsequently exploring the reactivity contribute
substantially to advance the main group element chemistry. Herein, we report on the …

Herein, we report the synthesis of a new sterically demanding hyper-coordinate
phosphasilene (Mes* PSi (SiMe3)(PhC (NtBu) 2)(1) and its unprecedented reactivity with …

The synthesis and isolation of stable heavier analogues of nitrile ylide as N-heterocyclic
carbene (NHC) adducts of phosphasilenyl-tetrylene [(NHC)(TerAr) Si (H) PE14 …

We predicted the stability, optical properties, and ability to store sodium of a novel two-
dimensional silicene-like material net-Y-Si by embedding both six-membered and four …

Synthesis of four and five coordinated aluminum amidinate (PhC (NtBu) 2= L) compounds
are reported herein along with their single‐crystal X‐ray structures and detailed …

The trapping of a transient base‐stabilized germylenylsilylene by elemental tellurium and
arylazide is described. The reaction of the potassium 2‐imino‐5, 6 …

The equilibrium geometry, bonding, and proton affinity of the pseudo‐silapnictenes and the
bis (pseudo‐silapnictenes) are explored using computational quantum mechanical …