The development of molecular materials with novel functionality offers promise for
technological innovation. Switchable molecules that incorporate redox‐active components …

Coordination of alcohols to the single-electron reductant samarium diiodide (SmI2) results in
substantial O–H bond weakening, affording potent proton-coupled electron transfer (PCET) …

Controlling product selectivity in multiproton, multielectron reductions of unsaturated small
molecules is of fundamental interest in catalysis. For the N2 reduction reaction (N2RR) in …

Following our report of the first near-linear lanthanide (Ln) complex,[Sm (N††) 2](1), herein
we present the synthesis of [Ln (N††) 2][N††={N (Si i Pr3) 2}; Ln= Eu (2), Tm (3), Yb (4)], thus …

Lanthanide (Ln) silylamide chemistry is well-developed, but the corresponding
silylphosphide chemistry is immature; there are only ten structurally characterized examples …

While lanthanide (Ln) silylamide chemistry is mature, the corresponding silylphosphide
chemistry is underdeveloped, with [Sm {P (SiMe3) 2}{μ-P (SiMe3) 2} 3Sm (THF) 3] being the …

The introduction of (N2) 3–• radicals into multinuclear lanthanide molecular magnets raised
hysteresis temperatures by stimulating strong exchange coupling between spin centers …

Reduction of tungsten hexacarbonyl by the divalent samarium (II) complex [Sm2 (N4Et8)(thf)
4]((N4Et8) 4−= meso‐octaethylcalix [4] pyrrolide) in toluene at ambient temperature gave the …

Copper isotopes and their complexes are intensively studied due to their high potential for
the application in radiodiagnosis and radiotherapy. Here we study the CuII complex of 1, 8 …

A new dinuclear Fe (III) complex,[Fe 2 (bp) 2 (N 3) 2] CH 3 OH (1), was synthesized by the
reaction of FeCl 2· 4H 2 O, NaN 3 and H 2 bp in methanol where H 2 bp is the bis …