Planar chiral [2.2] paracyclophanes: from synthetic curiosity to applications in asymmetric synthesis and materials

Z Hassan, E Spuling, DM Knoll, J Lahann… - Chemical Society …, 2018 - pubs.rsc.org
Planar chiral [2.2] paracyclophane-based ligands and employment of such enantiopure
representative ligands to facilitate selective transformation of prochiral or racemic …

Regioselective functionalization of [2.2] paracyclophanes: Recent synthetic progress and perspectives

Z Hassan, E Spuling, DM Knoll… - Angewandte Chemie …, 2020 - Wiley Online Library
2] Paracyclophane (PCP) is a prevalent scaffold that is widely utilized in asymmetric
synthesis, π‐stacked polymers, energy materials, and functional parylene coatings that finds …

Planar-chiral building blocks for metal–organic frameworks

M Cakici, ZG Gu, M Nieger, J Bürck, L Heinke… - Chemical …, 2015 - pubs.rsc.org
The first example of a planar-chiral building block being used for chiral metal–organic
frameworks (MOFs) is presented. The porous MOF structure combined with the chiral …

Binuclear zinc (II) complexes with the anti-inflammatory compounds salicylaldehyde semicarbazone and salicylaldehyde-4-chlorobenzoyl hydrazone (H2LASSBio …

GL Parrilha, RP Vieira, AP Rebolledo, IC Mendes… - Polyhedron, 2011 - Elsevier
Abstract Complexes [Zn 2 (HL 1) 2 (CH 3 COO) 2](1) and [Zn 2 (L 2) 2](2) were synthesized
with salicylaldehyde semicarbazone (H 2 L 1) and salicylaldehyde-4-chlorobenzoyl …

Structural Elucidation, Aggregation, and Dynamic Behaviour of N,N,N,N‐Copper(I) Schiff Base Complexes in Solid and in Solution: A Combined NMR, X‐ray …

I Gerz, SAV Jannuzzi, KT Hylland… - European Journal of …, 2021 - Wiley Online Library
A series of Cu (I) complexes of bidentate or tetradentate Schiff base ligands bearing either 1‐
H‐imidazole or pyridine moieties were synthesized. The complexes were studied by a …

Regioselektive Funktionalisierung von [2.2] Paracyclophanen: aktuelle Synthesefortschritte und Perspektiven

Z Hassan, E Spuling, DM Knoll, S Bräse - Angewandte Chemie, 2020 - Wiley Online Library
2] Paracyclophan (PCP) ist ein häufig genutztes Grundgerüst in der asymmetrischen
Synthese, in π‐gestapelten Polymeren, in Energiematerialien sowie in funktionellen …

Design of novel chiral N, N, O-tridentate phenanthroline ligands and their application to enantioselective addition of organozinc reagents to aldehydes

Y Naganawa, T Namba, T Aoyama, K Shoji… - Chemical …, 2014 - pubs.rsc.org
The novel N, N, O-tridentate phenanthroline ligand (BinThro) bearing an axially chiral
binaphthyl backbone prepared from BINOL was found to be an effective chiral catalyst for …

Metal‐to‐Metal Distance Modulated Au (I)/Ru (II) Cyclophanyl Complexes: Cooperative Effects in Photoredox Catalysis

C Zippel, R Israil, L Schüssler, Z Hassan… - … A European Journal, 2021 - Wiley Online Library
The modular synthesis of Au (I)/Ru (II) decorated mono‐and heterobimetallic complexes with
π‐conjugated [2.2] paracyclophane is described.[2.2] Paracyclophane serves as a rigid …

Mild preparation of functionalized [2.2] paracyclophanes via the Pummerer rearrangement

M Montanari, A Bugana, AK Sharma… - Organic & Biomolecular …, 2011 - pubs.rsc.org
[2.2] Paracyclophanes, incorporating functional groups in the aliphatic bridges, suitable for
elimination to give [2.2] paracyclophanedienes, are synthesized through a novel approach. It …

[2.2] Paracyclophane‐Derived Planar‐Chiral Hydrogen‐Bond Receptors

JF Schneider, R Froehlich… - Israel Journal of …, 2012 - Wiley Online Library
The development of planar‐chiral hydrogen‐bond donors based on the [2.2]
paracyclophane scaffold is discussed. General strategies to access functionalized …