A bulky 1, 4, 7-triazacyclononane and acetonitrile, a Goldilocks system for probing the role of NiIII and NiI centers in cross-coupling catalysis
In nickel-catalyzed cross-coupling reactions involving alkyl substrates, catalysts supported
by N-donor ligands are proposed to involve paramagnetic Ni (I) and Ni (III) species as key …
by N-donor ligands are proposed to involve paramagnetic Ni (I) and Ni (III) species as key …
Alkene Isomerization Using a Heterogeneous Nickel-Hydride Catalyst
AS Chang, MA Kascoutas, QP Valentine… - Journal of the …, 2024 - ACS Publications
Transition metal-catalyzed alkene isomerization is an enabling technology used to install an
alkene distal to its original site. Due to their well-defined structure, homogeneous catalysts …
alkene distal to its original site. Due to their well-defined structure, homogeneous catalysts …
Ring-opening polymerization of ε-caprolactone by Zr (IV) tris (β-diketonates): Electronic character of complexes in initiation and propagation steps
A series of zirconium β-diketonates, ie, tris (acetylacetonato) zirconium (IV) chloride (1), tris
(benzoylacetonato) zirconium (IV) chloride (2), tris (dibenzoylmethanato) zirconium (IV) …
(benzoylacetonato) zirconium (IV) chloride (2), tris (dibenzoylmethanato) zirconium (IV) …
One-Step Green Synthesis of Isoeugenol Methyl Ether from Eugenol by Dimethyl Carbonate and Phase-Transfer Catalysts
Z Zhang, Y Gong, X Xue, M Hu, M Zhou, Y Zhao, Z Hu - Molecules, 2024 - mdpi.com
In this paper, the green synthesis of isoeugenol methyl ether (IEME) from eugenol by O-
methylation and isomerization is completed using a one-step green process. In the …
methylation and isomerization is completed using a one-step green process. In the …