Tris (pyrazolyl) borates (Tp x) have become one of the most broadly used polydentate
anionic ligands in coordination chemistry and catalysis since Trofimenko introduced them in …

Chemistry of the p-block elements with anionic scorpionate ligands - ScienceDirect Skip to
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Heteroleptic silylamido complexes of the heavier alkaline earth elements calcium and
strontium containing the highly fluorinated 3‐phenyl hydrotris (indazolyl) borate {F12 …

The importance of electron deficient Tp ligands motivates the introduction of electron-
withdrawing substituents into the scorpionate framework. Since perfluorophenyltris (pyrazol …

The development of catalytic methods for the effective functionalization of methane yet
remains a challenge. The best system known to date is the so‐called Catalytica Process …

1H-Indazole derivatives exhibit a remarkable property since some of them form chiral
supramolecular structures starting from achiral monomers. The present work deals with the …

Heteroleptic phenylacetylide complexes [{F12-Tp4Bo, 3Ph} Ae (C CPh)] x of calcium (Ae=
Ca, x= 2; 2) and magnesium (Ae= Mg, x= 1; 4) containing the highly fluorinated 3-phenyl …

This chapter provides an account of the use of copper and silver complexes with
trispyrazolylborate as ancillary ligand for homogeneous catalysis in a series of …

Two series of highly fluorinated 3-substituted hydrotris (indazolyl) borate (Fn-Tp4Bo, 3R; R=
Ph, n= 12; R= CF3, n= 21) complexes of calcium were synthesized by salt metathesis …

This work reports the behavior in solution and in the solid-state of the title compound, a
known but neglected benzotriazole. In solution, we have measured the prototropic barrier …