Fluorine sites in calcium and barium oxyfluorides: F-19 NMR on crystalline model compounds and glasses

TJ Kiczenski, JF Stebbins - Journal of Non-Crystalline Solids, 2002 - Elsevier
As part of an ongoing effort to apply Fluorine-19 NMR to understanding the effects of fluoride
on the structures and properties of silicate glasses and melts, the local environment of …

First Crystal Structure Studies of CaAlH5

C Weidenthaler, TJ Frankcombe… - Inorganic …, 2006 - ACS Publications
A new member of the aluminum hydride family, CaAlH5, is formed during the decomposition
of Ca (AlH4) 2. The crystal structure of this new compound was calculated by density …

Luminescence excitation study of the higher energy states of and in , , and

E Van der Kolk, P Dorenbos, CWE Van Eijk… - Journal of applied …, 2004 - pubs.aip.org
The possibility to use Mn 2+ co-doping to modify the emission properties of Pr 3+-based
quantum cutting phosphors—ie, phosphors that emit one UV and one visible photon for …

Correlation between 19F Environment and Isotropic Chemical Shift in Barium and Calcium Fluoroaluminates

M Body, G Silly, C Legein, JY Buzaré - Inorganic chemistry, 2004 - ACS Publications
High-speed MAS 19F NMR spectra are recorded and reconstructed for 10 compounds from
BaF2− AlF3 and CaF2− AlF3 binary systems which leads to the determination of 77 isotropic …

Homonuclear dipolar recoupling under ultra-fast magic-angle spinning: Probing 19F− 19F proximities by solid-state NMR

Q Wang, B Hu, O Lafon, J Trébosc, F Deng… - Journal of Magnetic …, 2010 - Elsevier
We describe dipolar recoupling methods that accomplish, at high magic-angle spinning
(MAS) frequencies, the excitation of double-quantum (DQ) coherences between spin-1/2 …

New alkaline earth aluminium fluorides with the formula (M, M′) AlF5 (M, M′= Ca, Sr, Ba)

M Weil, E Zobetz, F Werner, F Kubel - Solid state sciences, 2001 - Elsevier
Two new modifications, α′-SrAlF5 and δ-BaAlF5, as well as two solid solutions, Ca0.
08Sr0. 92AlF5 and Ca0. 33Sr0. 67AlF5, have been synthesized in the system (M, M′) …

Double-quantum 19 F–19 F dipolar recoupling at ultra-fast magic angle spinning NMR: application to the assignment of 19F NMR spectra of inorganic fluorides

Q Wang, B Hu, F Fayon, J Trébosc, C Legein… - Physical Chemistry …, 2009 - pubs.rsc.org
Double-quantum 19 F– 19 F dipolar recoupling at ultra-fast magic angle spinning NMR :
application to the assignment of 19F NMR spectra of inorganic f ... - Physical Chemistry Chemical …

LEONARDSENITE, MgAlF5(H2O)2, A NEW MINERAL SPECIES FROM ELDFELL VOLCANO, HEIMAEY ISLAND, ICELAND

D Mitolo, A Garavelli, T Balić-Žunić… - The Canadian …, 2013 - pubs.geoscienceworld.org
Abstract Leonardsenite (IMA2011-059), with ideal formula MgAlF5 (H2O) 2, is a new
fumarole mineral from Eldfell volcano, Iceland. It has also been found in volcanic …

Advances in Structural Analysis of Fluoroaluminates Using DFT Calculations of 27Al Electric Field Gradients

M Body, C Legein, JY Buzaré, G Silly… - The Journal of …, 2007 - ACS Publications
Based on the analysis of 23 aluminum sites from 16 fluoroaluminates, the present work
demonstrates the strong potential of combining accurate NMR quadrupolar parameter …

On the assignment of 19 F MAS NMR spectra of fluoroaluminates using through-space spectral edition of 19 F–27 Al and 19 F–19 F connectivities

C Martineau, C Legein, JY Buzaré… - Physical Chemistry …, 2009 - pubs.rsc.org
Advantages and limitations of 19F–27Al and 19F–19F dipolar-based 2D NMR experiments
for 19F MAS spectra assignments of fluoroaluminates are presented. In β-BaAlF5 …