Exploring Cationic Substitutions in the Solid Electrolyte NaAlCl4 with Density Functional Theory

M Häfner, M Bianchini - The Journal of Physical Chemistry C, 2024 - ACS Publications
NaAlCl4 is an established solid electrolyte in high-temperature Na-based battery systems,
but its ionic conductivity is not sufficiently high for room-temperature applications. We …

Metal assisted synthesis of cationic sulfidobismuth cubanes in ionic liquids

M Knies, MF Groh, T Pietsch, M Lê Anh… - ChemistryOpen, 2021 - Wiley Online Library
Bi2S3 was dissolved in the presence of either AuCl/PtCl2 or AgCl in the ionic liquids [BMIm]
Cl⋅ xAlCl3 (BMIm= 1‐n‐butyl‐3‐methylimidazolium; x= 4–4.3) through annealing the …

Solubilities, structures, and speciations of bimetallic composite ionic liquids: X-ray absorption fine structure and density functional theory calculations

Y Zhang, R Zhang, L Wu, H Liu, Z Liu… - Industrial & …, 2021 - ACS Publications
Bimetallic composite ionic liquids (ILs) show outstanding performance in catalysis and
material fields. The unambiguous identifications of their structures are fundamental to …

Synthesis, structure, and photoluminesence of the chloridoaluminates [BMIm][Sn (AlCl 4) 3],[BMPyr][Sn (AlCl 4) 3], and [BMIm][Pb (AlCl 4) 3]

S Wolf, M Liebertseder, C Feldmann - Dalton Transactions, 2021 - pubs.rsc.org
[BMIm][Sn (AlCl4) 3](1)([BMIm]: 1-butyl-3-methylimidazolium),[BMPyr][Sn (AlCl4)
3](2)([BMPyr]: 1-butyl-1-methyl-pyrrolidinium), and [BMIm][Pb (AlCl4) 3](3) are obtained by …

Salts of octabismuth (2+) polycations crystallized from Lewis-acidic ionic liquids

M Knies, M Ruck - Zeitschrift für Naturforschung B, 2021 - degruyter.com
The reaction of Bi and BiCl3 with RbCl or CsCl in the Lewis-acidic ionic liquid (IL)[BMIm] Cl·
4AlCl3 at T= 200° C yielded air-sensitive, shiny black crystals. X-ray diffraction on single …

Tin Bromido Aluminate Networks with Bright Luminescence

S Wolf, R Köppe, PW Roesky, C Feldmann - ChemistryOpen, 2023 - Wiley Online Library
The novel tin bromido aluminates [Sn3 (AlBr4) 6](Al2Br6)(1), Sn (AlBr4) 2 (2),[EMIm][Sn
(AlBr4) 3](3) and [BMPyr][Sn (AlBr4) 3](4)([EMIm]: 1‐ethyl‐3‐methylimidazolium,[BMPyr]: 1 …

Observation of a New Polyhalide Phase in Ag-Cl2 System at High Pressure

A Grzelak, J Gawraczyński, M Derzsi, V Struzhkin… - Crystals, 2021 - mdpi.com
In this short contribution, we examine Raman spectroscopic data from high-pressure and
high-temperature experiments with an Ag-Cl2 system, and find that they are in good …

[图书][B] Synthesestrategien zu neuen metastabilen Materialien am Beispiel nanoskaliger Hohlkugeln und komplexer Halogenidometallate

M Liebertseder - 2021 - books.google.com
Ziel dieser Arbeit war die Entwicklung von Synthesekonzepten, zum einen zur Herstellung
von nanoskaligen Hohlkugeln und zum anderen zur Synthese komplexer …