This review serves to document advances in the synthesis, versatile bonding, and reactivity
of molecular main group metal hydrides within Groups 1, 2, and 12–16. Particular attention …

Over the past three decades, the field of coordination polymers (CPs) and metal–organic
frameworks (MOFs) has developed rapidly due to the potential applications of these …

Controlled ligand‐based redox‐activity and chemical non‐innocence are rapidly gaining
importance for selective (catalytic) processes. This Concept aims to provide an overview of …

Hydrogen emerges as one of the cleanest and most renewable energy resources for fossil
fuel alternatives. Commercial-scale hydrogen production through water-splitting …

The catalytic reduction of CO2 to HCO2–requires a formal transfer of a hydride (two
electrons, one proton). Synthetic approaches for inorganic molecular catalysts have …

In this study, we report the electrocatalytic behavior of the neutral, monomeric Cu (II)
complex of diacetyl-bis (N-4-methyl-3-thiosemicarbazonato), CuL1, for metal-assisted ligand …

The present Minireview highlights the most representative and emerging developments
reported since 2012 on the use of well‐defined group 13 metal species in homogeneous …

Electrocatalytic hydrogen evolution reaction (HER) is a critical process in a sustainable
energy conversion system. Many metal complexes as small-molecule catalysts for …

The hydrogenation of CO2 in the presence of amines to formate, formamides, and methanol
(MeOH) is a promising approach to streamlining carbon capture and recycling. To achieve …

In this study, we report the electrocatalytic behavior of the neutral, monomeric Ni (II) complex
of diacetyl-bis (N-4-methyl-3-thiosemicarbazonato), NiL1, for ligand-assisted metal-centered …