An evolving view on biogeochemical cycling of iron

A Kappler, C Bryce, M Mansor, U Lueder… - Nature Reviews …, 2021 - nature.com
Biogeochemical cycling of iron is crucial to many environmental processes, such as ocean
productivity, carbon storage, greenhouse gas emissions and the fate of nutrients, toxic …

Fe (II) redox chemistry in the environment

J Huang, A Jones, TD Waite, Y Chen, X Huang… - Chemical …, 2021 - ACS Publications
Iron (Fe) is the fourth most abundant element in the earth's crust and plays important roles in
both biological and chemical processes. The redox reactivity of various Fe (II) forms has …

Magnetite and green rust: synthesis, properties, and environmental applications of mixed-valent iron minerals

M Usman, JM Byrne, A Chaudhary, S Orsetti… - Chemical …, 2018 - ACS Publications
Mixed-valent iron [Fe (II)-Fe (III)] minerals such as magnetite and green rust have received a
significant amount of attention over recent decades, especially in the environmental …

Schwertmannite: A review of its occurrence, formation, structure, stability and interactions with oxyanions

VA Schoepfer, ED Burton - Earth-Science Reviews, 2021 - Elsevier
In this article, we provide a critical review on the occurrence, formation, structure and stability
of schwertmannite–an enigmatic Fe (III) oxyhydroxy-sulfate mineral that is of widespread …

Electron transfer, atom exchange, and transformation of iron minerals in soils: the influence of soil organic matter

C Chen, Y Dong, A Thompson - Environmental Science & …, 2023 - ACS Publications
Despite substantial experimental evidence of electron transfer, atom exchange, and
mineralogical transformation during the reaction of Fe (II) aq with synthetic Fe (III) minerals …

Organic amendments for in situ immobilization of heavy metals in soil: A review

J Gao, H Han, C Gao, Y Wang, B Dong, Z Xu - Chemosphere, 2023 - Elsevier
There is a growing need for soil remediation due to the increase in heavy metals (HMs)
migrating into the soil environment, especially those from man-made sources dominated by …

Synchronous sequestration of cadmium and fulvic acid by secondary minerals from Fe (II)-catalyzed ferrihydrite transformation

S Hu, L Zhen, S Liu, C Liu, Z Shi, F Li, T Liu - Geochimica et Cosmochimica …, 2022 - Elsevier
As consequence of the dual demands for pollution control and carbon (C) fixation in soils, Fe
(II)-catalyzed mineral transformation may be a promising method to simultaneously …

Coexisting goethite promotes Fe (II)-catalyzed transformation of ferrihydrite to goethite

L Notini, LK ThomasArrigo, R Kaegi… - … Science & Technology, 2022 - ACS Publications
In redox-affected soil environments, electron transfer between aqueous Fe (II) and solid-
phase Fe (III) catalyzes mineral transformation and recrystallization processes. While these …

Impact of organic matter on iron (II)-catalyzed mineral transformations in ferrihydrite–organic matter coprecipitates

LK ThomasArrigo, JM Byrne, A Kappler… - … science & technology, 2018 - ACS Publications
Poorly crystalline Fe (III)(oxyhydr) oxides like ferrihydrite are abundant in soils and
sediments and are often associated with organic matter (OM) in the form of mineral-organic …

Direct interspecies electron transfer accelerates syntrophic oxidation of butyrate in paddy soil enrichments

H Li, J Chang, P Liu, L Fu, D Ding… - Environmental …, 2015 - Wiley Online Library
Syntrophic interaction occurs during anaerobic fermentation of organic substances forming
methane as the final product. H 2 and formate are known to serve as the electron carriers in …