This review discusses the heteroatom-containing dioxiranes in organic chemistry.
Heteroatom-containing dioxiranes are three-membered ring peroxides with the form XO2 …

The main developments in rational construction of chiral metallo-aggregates based on
octahedral metal complexes with 2-aminoethanethiolate (aet) or l-cysteinate (l-cys), as well …

The violet color of Pt (bpy)(bdt)(bpy= 2, 2 '-bipyridine; bdt= 1, 2-benzenedithiolate) is due to
a Pt/S→ diimine charge-transfer transition; the emission originates from the corresponding …

As part of our work on models of the iron (III) site of Fe-containing nitrile hydratase, a
designed ligand PyPSH4 with two carboxamide and two thiolate donor groups has been …

The synthesis of structural and functional models of the active site of the nonheme iron
enzyme cysteine dioxygenase (CDO) is reported. A bis (imino) pyridine ligand scaffold was …

A photochemical and photophysical investigation was carried out on (tbubpy) PtII (dpdt) and
(tbubpy) PtII (edt)(1 and 2, respectively, where tbubpy= 4, 4 '-di-tert-butyl-2, 2 '-bipyridine …

We disclose a suite of Ni (II) complexes featuring secondary sphere Lewis acids of varied
Lewis acidity and tether lengths. Several of these complexes feature atypical behavior of Ni …

[Pd (bpy)(bdt)], 2 (bpy= 2, 2 '-bipyridine, bdt= 1, 2-benzenedithiolate), was prepared in good
yield by the reaction of bdtNa2 with [(bpy) PdCl2] in DMSO. The analogous nickel complex …

Metal thiolate complexes can act as photosensitizers for the generation of singlet oxygen,
quenchers of singlet oxygen, and they may undergo chemical reactions with singlet oxygen …

Nonheme iron (III)-superoxo intermediates are generated in the activation of dioxygen (O2)
by nonheme iron (II) complexes and then converted to iron (IV)-oxo species by reacting with …