Phosphorus compounds bearing chirality on the P-center are usually qualified as P-
chirogenic or P-stereogenic. This chemical class concerns natural products, agrochemistry …

Despite the impressive progress achieved in asymmetric catalysis during the last decade, an
increasing number of new catalysts, ligands, and applications are reported every year to …

The practical synthesis of P-stereogenic tertiary phosphines, which have wide applications
in asymmetric catalysis, materials, and pharmaceutical chemistry, represents a significant …

Catalytic synthesis of nonracemic P-chiral phosphine derivatives remains a significant
challenge. Here we report Cu-catalyzed enantioselective arylation of secondary phosphine …

Underappreciated in the realm of palladium catalyzed cross-coupling chemistry is the
formation of phosphorous–carbon bonds. This tutorial review summarises a collection of …

A nickel-catalyzed asymmetric allylation of secondary phosphine oxides (SPO) for the
synthesis of tertiary phosphine oxides (TPO) was realized with high enantioselectivity. The …

This review describes the main synthetic methodologies available for the preparation of P-
stereogenic phosphines and derivatives. The literature coverage focuses in the last ten …

Chiral phosphanes, important ligands for metal‐catalyzed asymmetric syntheses, are often
prepared with compounds from the chiral pool, by using stoichiometric chiral auxiliaries, or …

An efficient olefinic C–P cross-coupling of alkenylsulfonium salts with secondary
diarylphosphines is reported. The use of a palladacycle enables the facile formation of a C …

This review is a comprehensive account of transition-metal-catalyzed cross-coupling
reactions to form CP bonds. Organized according to the hybridization of the carbon coupling …