Comprehensive H2/O2 kinetic model for high‐pressure combustion

MP Burke, M Chaos, Y Ju, FL Dryer… - … Journal of Chemical …, 2012 - Wiley Online Library
An updated H2/O2 kinetic model based on that of Li et al.(Int J Chem Kinet 36, 2004, 566–
575) is presented and tested against a wide range of combustion targets. The primary …

A critical review of radiolysis issues in water-cooled fission and fusion reactors: Part I, assessment of radiolysis models

DD Macdonald, GR Engelhardt, A Petrov - Corrosion and Materials …, 2022 - mdpi.com
A critical review is presented on modeling of the radiolysis of the coolant water in nuclear
power reactors with emphasis on ITER. The review is presented in two parts: In Part I, we …

Critical review of aqueous solution reaction rate constants for hydrogen atoms

KP Madden, SP Mezyk - Journal of Physical and Chemical Reference …, 2011 - pubs.aip.org
Kinetic data published in the peer-reviewed literature over the period of 1988–2007 for H⋅
radical reactions with molecules and ions derived from inorganic and organic solutes in …

The reaction set, rate constants and g-values for the simulation of the radiolysis of light water over the range 20 deg to 350 deg C based on information available in …

AJ Elliot, DM Bartels - 2009 - inis.iaea.org
An understanding of the aqueous radiolysis-induced chemistry in nuclear reactors is an
important key to the understanding of materials integrity issues in reactor systems …

Photoenhanced Radical Formation in Aqueous Mixtures of Levoglucosan and Benzoquinone: Implications to Photochemical Aging of Biomass-Burning Organic …

L Gerritz, M Schervish, PSJ Lakey, T Oeij… - The Journal of …, 2023 - ACS Publications
The photochemical aging of biomass-burning organic aerosols (BBOAs) by exposure to
sunlight changes the chemical composition over its atmospheric lifetime, affecting the …

Experimental and modelling study of the recombination reaction H+ O 2 (+ M)→ HO 2 (+ M) between 300 and 900 K, 1.5 and 950 bar, and in the bath gases M= He, Ar …

RX Fernandes, K Luther, J Troe… - Physical Chemistry …, 2008 - pubs.rsc.org
The recombination reaction H+ O2 (+ M)→ HO2 (+ M) was studied by laser flash photolysis
in a high pressure flow cell, over the temperature range 300–900 K, the pressure range 1.5 …

Hydroxyl radical self-recombination reaction and absorption spectrum in water up to 350 C

I Janik, DM Bartels, CD Jonah - The Journal of Physical Chemistry …, 2007 - ACS Publications
The rate constant for the self-recombination of hydroxyl radicals (• OH) in aqueous solution
giving H2O2 product has been measured from 150 to 350° C by direct measurement of the• …

Reaction of the hydroxyl radical with phenol in water up to supercritical conditions

J Bonin, I Janik, D Janik, DM Bartels - The Journal of Physical …, 2007 - ACS Publications
The rate constants for the reactions of phenol with the hydroxyl radical (OH•) in water have
been measured from room temperature to 380° C using electron pulse radiolysis and …

Development of a Detailed Kinetic Model for Hydrogen Oxidation in Supercritical H2O/CO2 Mixtures

G Li, Y Lu, P Glarborg - Energy & Fuels, 2020 - ACS Publications
The application of hydrogen as a fuel or auxiliary fuel has extended beyond gas-phase
conditions. This paper reports the development of a detailed chemical kinetic model for …

Reaction kinetics for high pressure hydrogen oxy-combustion in the presence of high levels of H2O and CO2

A Beigzadeh, M Alabbad, D Liu, K Aljohani… - Combustion and …, 2023 - Elsevier
Novel shock tube experimental ignition delay time (IDT) data are provided to delineate the
impact of high concentrations (45% by mole) of H 2 O and CO 2 on IDTs of stoichiometric 4 …