Electrochemical Reduction of CO2 to CO over Transition Metal/N‐Doped Carbon Catalysts: The Active Sites and Reaction Mechanism

S Liang, L Huang, Y Gao, Q Wang, B Liu - Advanced Science, 2021 - Wiley Online Library
Electrochemical CO2 reduction to value‐added chemicals/fuels provides a promising way to
mitigate CO2 emission and alleviate energy shortage. CO2‐to‐CO conversion involves only …

Active site engineering in porous electrocatalysts

H Chen, X Liang, Y Liu, X Ai, T Asefa… - Advanced …, 2020 - Wiley Online Library
Electrocatalysis is at the center of many sustainable energy conversion technologies that are
being developed to reduce the dependence on fossil fuels. The past decade has witnessed …

Electroreduction of Carbon Dioxide Driven by the Intrinsic Defects in the Carbon Plane of a Single Fe–N4 Site

W Ni, Z Liu, Y Zhang, C Ma, H Deng… - Advanced …, 2021 - Wiley Online Library
Manipulating the in‐plane defects of metal–nitrogen–carbon catalysts to regulate the
electroreduction reaction of CO2 (CO2RR) remains a challenging task. Here, it is …

Elucidating electrochemical nitrate and nitrite reduction over atomically-dispersed transition metal sites

E Murphy, Y Liu, I Matanovic, M Rüscher… - Nature …, 2023 - nature.com
Electrocatalytic reduction of waste nitrates (NO3−) enables the synthesis of ammonia (NH3)
in a carbon neutral and decentralized manner. Atomically dispersed metal-nitrogen-carbon …

Highly Durable and Selective Fe- and Mo-Based Atomically Dispersed Electrocatalysts for Nitrate Reduction to Ammonia via Distinct and Synergized NO2 …

E Murphy, Y Liu, I Matanovic, S Guo, P Tieu… - ACS …, 2022 - ACS Publications
Aimed toward the pursuit of manufacturing ammonia in a carbon-neutral and decentralized
manner, the electrocatalytic nitrate reduction reaction (NO3RR) not only promises an …

Regulating nonmetallic species beyond the first coordination shell of single-atom catalysts for high-performance electrocatalysis

W Ni, H Chen, J Zeng, Y Zhang, HA Younus… - Energy & …, 2023 - pubs.rsc.org
The local microenvironment of single-atom electrocatalysts (SACs) governs their activity and
selectivity. While previous studies have focused on the first coordination shell (FCS) of metal …

Highly Dispersed NiO Clusters Induced Electron Delocalization of NiNC Catalysts for Enhanced CO2 Electroreduction

H Li, K Gan, R Li, H Huang, J Niu… - Advanced Functional …, 2023 - Wiley Online Library
Oxygen‐regulated Ni‐based single‐atom catalysts (SACs) show great potential in
accelerating the kinetics of electrocatalytic CO2 reduction reaction (CO2RR). However, it …

Pyrrolic N‐Stabilized Monovalent Ni Single‐Atom Electrocatalyst for Efficient CO2 Reduction: Identifying the Role of Pyrrolic–N and Synergistic Electrocatalysis

R Boppella, M Austeria P, Y Kim, E Kim… - Advanced Functional …, 2022 - Wiley Online Library
Engineering the electronic structure of metal, N‐doped carbon catalysts is a potential
strategy for increasing the activity and selectivity of CO2 electroreduction reaction (CO2RR) …

Carbon‐Supported Single Metal Site Catalysts for Electrochemical CO2 Reduction to CO and Beyond

Y Zhu, X Yang, C Peng, C Priest, Y Mei, G Wu - Small, 2021 - Wiley Online Library
The electrochemical CO2 reduction reaction (CO2RR) is a promising strategy to achieve
electrical‐to‐chemical energy storage while closing the global carbon cycle. The carbon …

Does the Oxygen Evolution Reaction follow the classical OH*, O*, OOH* path on single atom catalysts?

I Barlocco, LA Cipriano, G Di Liberto, G Pacchioni - Journal of Catalysis, 2023 - Elsevier
Abstract The Oxygen Evolution Reaction (OER) is a key part of water splitting. On metal and
oxide surfaces it usually occurs via formation of three intermediates, M (OH), M (O), and M …