Light olefin synthesis from a diversity of renewable and fossil feedstocks: state-of the-art and outlook

SA Chernyak, M Corda, JP Dath… - Chemical Society …, 2022 - pubs.rsc.org
Light olefins are important feedstocks and platform molecules for the chemical industry.
Their synthesis has been a research priority in both academia and industry. There are many …

Heterogeneous alkane dehydrogenation catalysts investigated via a surface organometallic chemistry approach

SR Docherty, L Rochlitz, PA Payard… - Chemical Society …, 2021 - pubs.rsc.org
The selective conversion of light alkanes (C2–C6 saturated hydrocarbons) to the
corresponding alkene is an appealing strategy for the petrochemical industry in view of the …

Propane Dehydrogenation on Ga2O3-Based Catalysts: Contrasting Performance with Coordination Environment and Acidity of Surface Sites

P Castro-Fernández, D Mance, C Liu, IB Moroz… - ACS …, 2021 - ACS Publications
α-Ga2O3, β-Ga2O3, and γ-Ga2O3 as well as the silica-supported catalysts γ-Ga2O3/SiO2, β-
Ga2O3/SiO2, and Ga (NO3) 3-derived Ga/SiO2 were prepared, characterized, and …

Promoting active site renewal in heterogeneous olefin metathesis catalysts

TZH Gani, ZJ Berkson, R Zhu, JH Kang, JR Di Iorio… - Nature, 2023 - nature.com
As an atom-efficient strategy for the large-scale interconversion of olefins, heterogeneously
catalysed olefin metathesis sees commercial applications in the petrochemical, polymer and …

Dynamics and site isolation: keys to high propane dehydrogenation performance of silica-supported PtGa nanoparticles

PA Payard, L Rochlitz, K Searles, L Foppa, B Leuthold… - Jacs Au, 2021 - ACS Publications
Nonoxidative dehydrogenation of light alkanes has seen a renewed interest in recent years.
While PtGa systems appear among the most efficient catalyst for this reaction and are now …

Recent progress in catalytic dehydrogenation of propane over Pt-based catalysts

Y Shan, H Hu, X Fan, Z Zhao - Physical Chemistry Chemical Physics, 2023 - pubs.rsc.org
Light alkenes are the key building blocks in the chemical industry. As a propene on-purpose
production technology, propane dehydrogenation has drawn particular attention due to the …

Direct Detection of Reactive Gallium-Hydride Species on the Ga2O3 Surface via Solid-State NMR Spectroscopy

H Chen, P Gao, Z Liu, L Liang, Q Han… - Journal of the …, 2022 - ACS Publications
Surface metal hydrides (M–H) are ubiquitous in heterogeneous catalytic reactions, while the
detailed characterizations are frequently hindered by their high reactivity/low concentration …

Olefin oligomerization by main group Ga3+ and Zn2+ single site catalysts on SiO2

NJ LiBretto, Y Xu, A Quigley, E Edwards… - Nature …, 2021 - nature.com
In heterogeneous catalysis, olefin oligomerization is typically performed on immobilized
transition metal ions, such as Ni2+ and Cr3+. Here we report that silica-supported, single …

The active sites and catalytic properties of CrOx/Zn-Al2O3 catalysts for propane dehydrogenation

H Shao, Q He, D Wang, Y Zhang, T Jiang… - Applied Catalysis A …, 2022 - Elsevier
The CrO x-based catalysts supported on Zn-modified alumina were prepared for propane
dehydrogenation. The CrO x/Zn-Al 2 O 3 catalysts possess uniform foamed pores with high …

Computational investigation of the role of active site heterogeneity for a supported organovanadium (iii) hydrogenation catalyst

P Patel, RH Wells, DM Kaphan, M Delferro… - ACS …, 2021 - ACS Publications
A crucial consideration for supported heterogeneous catalysts is the nonuniformity of the
active sites, particularly for supported organometallic catalysts. Standard spectroscopic …