Alkene-derived radical cations are versatile reactive intermediates and have been widely
applied in the construction of complex functionalized molecules and cyclic systems for …

Supramolecular cage chemistry is of lasting interest because, as artificial blueprints of
natural enzymes, the self-assembled cage structures not only provide substrate-hosting …

In the field of synthetic organic chemistry, photochemical and electrochemical approaches
are often considered to be competing technologies that induce single electron transfer …

Herein we report the first high turnover photocatalytic hydrogen formation reaction based on
an earth-abundant FeIII-NHC photosensitiser. The reaction occurs via reductive quenching …

Carbon dioxide (CO 2) conversion into carbonates is one of the important ways to reduce
carbon emissions. In this study, several phosphonium-based functional deep eutectic …

Green-light-driven FeIII (btz) 3 photocatalysis for the radical cationic [4+ 2] cycloaddition of
terminal styrenes and nucleophilic dienes has been investigated. The Fe-MIC (mesoionic …

Single-electron oxidation and α-deprotonation of tertiary anilines using Fe (phen) 3 (PF6) 3
afford α-aminoalkyl radicals, which can be coupled with electrophilic partners to afford …

The oxidative alkenylation reaction of α-aminoalkyl C (sp3)–H bonds has been investigated
with (E)-1, 2-bis (sulfonyl) ethenes. The catalytic process of iron-polypyridyl complexes …

The FeIII (phen) 3 catalysis of the benzylic C (sp3)–H azidation of indoles has been
investigated. The Fe (III) complex can selectively oxidize indoles to form arene radical …

This paper describes the isolation and characterization of an aromatic radical cation
generated by FeCl3. X-ray crystallographic analysis and kinetic studies reveal the …